Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]

The title complex, [Cd(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], forms a dimer of the paddle-wheel type, located on a crystallographic inversion centre. The Cd(II) ion is hexa­coordinated by four carboxylate O atoms [Cd⋯O = 2.280 (2)–2.404 (2) Å] from two chelating 4-methoxy­benzoate anions, and two...

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Detalles Bibliográficos
Autor principal: Zhao, Dian-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983921/
https://www.ncbi.nlm.nih.gov/pubmed/21580526
http://dx.doi.org/10.1107/S1600536810009505
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author Zhao, Dian-Ying
author_facet Zhao, Dian-Ying
author_sort Zhao, Dian-Ying
collection PubMed
description The title complex, [Cd(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], forms a dimer of the paddle-wheel type, located on a crystallographic inversion centre. The Cd(II) ion is hexa­coordinated by four carboxylate O atoms [Cd⋯O = 2.280 (2)–2.404 (2) Å] from two chelating 4-methoxy­benzoate anions, and two N atoms [Cd⋯N = 2.313 (2) and 2.332 (2) Å] from one chelating 2,2′-dimethyl-3,3′-(oxydiethyl­ene)bis­(1H-benzimidazole) ligand. In the crystal, mol­ecules are linked by a weak inter­molecular C—H⋯O hydrogen bond and an inter­molecular C—H⋯π inter­action.
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spelling pubmed-29839212010-12-30 Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)] Zhao, Dian-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], forms a dimer of the paddle-wheel type, located on a crystallographic inversion centre. The Cd(II) ion is hexa­coordinated by four carboxylate O atoms [Cd⋯O = 2.280 (2)–2.404 (2) Å] from two chelating 4-methoxy­benzoate anions, and two N atoms [Cd⋯N = 2.313 (2) and 2.332 (2) Å] from one chelating 2,2′-dimethyl-3,3′-(oxydiethyl­ene)bis­(1H-benzimidazole) ligand. In the crystal, mol­ecules are linked by a weak inter­molecular C—H⋯O hydrogen bond and an inter­molecular C—H⋯π inter­action. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983921/ /pubmed/21580526 http://dx.doi.org/10.1107/S1600536810009505 Text en © Dian-Ying Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Dian-Ying
Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]
title Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]
title_full Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]
title_fullStr Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]
title_full_unstemmed Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]
title_short Bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1H-benzimidazole)-κ(2) N (3):N (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) O,O′)cadmium(II)]
title_sort bis[μ-2,2′-dimethyl-1,1′-(oxydiethyl­ene)bis­(1h-benzimidazole)-κ(2) n (3):n (3′)]bis­[bis­(4-methoxy­benzoato-κ(2) o,o′)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983921/
https://www.ncbi.nlm.nih.gov/pubmed/21580526
http://dx.doi.org/10.1107/S1600536810009505
work_keys_str_mv AT zhaodianying bism22dimethyl11oxydiethylenebis1hbenzimidazolek2n3n3bisbis4methoxybenzoatok2oocadmiumii

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