Cargando…

4-tert-Butyl­pyridinium picrate

In the title compound, C(9)H(14)N(+)·C(6)H(2)N(3)O(7) (−), the three nitro groups of the picrate anion are twisted out of the plane of the attached benzene ring; the dihedral angles are 32.8 (2), 10.5 (4) and 12.3 (4)°. The pyridinium cations and picrate anions are linked via bifurcated N—H⋯(O,O) hy...

Descripción completa

Detalles Bibliográficos
Autores principales: Ramesh, P., Akalya, R., Chandramohan, A., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983922/
https://www.ncbi.nlm.nih.gov/pubmed/21580795
http://dx.doi.org/10.1107/S1600536810011037
_version_ 1782191990844162048
author Ramesh, P.
Akalya, R.
Chandramohan, A.
Ponnuswamy, M. N.
author_facet Ramesh, P.
Akalya, R.
Chandramohan, A.
Ponnuswamy, M. N.
author_sort Ramesh, P.
collection PubMed
description In the title compound, C(9)H(14)N(+)·C(6)H(2)N(3)O(7) (−), the three nitro groups of the picrate anion are twisted out of the plane of the attached benzene ring; the dihedral angles are 32.8 (2), 10.5 (4) and 12.3 (4)°. The pyridinium cations and picrate anions are linked via bifurcated N—H⋯(O,O) hydrogen bonds. The ionic pairs are linked into a ribbon-like structure along [101] by C—H⋯O hydrogen bonds.
format Text
id pubmed-2983922
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29839222010-12-30 4-tert-Butyl­pyridinium picrate Ramesh, P. Akalya, R. Chandramohan, A. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(14)N(+)·C(6)H(2)N(3)O(7) (−), the three nitro groups of the picrate anion are twisted out of the plane of the attached benzene ring; the dihedral angles are 32.8 (2), 10.5 (4) and 12.3 (4)°. The pyridinium cations and picrate anions are linked via bifurcated N—H⋯(O,O) hydrogen bonds. The ionic pairs are linked into a ribbon-like structure along [101] by C—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983922/ /pubmed/21580795 http://dx.doi.org/10.1107/S1600536810011037 Text en © Ramesh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramesh, P.
Akalya, R.
Chandramohan, A.
Ponnuswamy, M. N.
4-tert-Butyl­pyridinium picrate
title 4-tert-Butyl­pyridinium picrate
title_full 4-tert-Butyl­pyridinium picrate
title_fullStr 4-tert-Butyl­pyridinium picrate
title_full_unstemmed 4-tert-Butyl­pyridinium picrate
title_short 4-tert-Butyl­pyridinium picrate
title_sort 4-tert-butyl­pyridinium picrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983922/
https://www.ncbi.nlm.nih.gov/pubmed/21580795
http://dx.doi.org/10.1107/S1600536810011037
work_keys_str_mv AT rameshp 4tertbutylpyridiniumpicrate
AT akalyar 4tertbutylpyridiniumpicrate
AT chandramohana 4tertbutylpyridiniumpicrate
AT ponnuswamymn 4tertbutylpyridiniumpicrate