(meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]

The title compound, [Cu(C(16)H(32)N(4))](C(14)H(14)O(2)PS(2))(2) or [Cu(trans[14]dien)][S(2)P(OC(6)H(4)Me-4)(2)](2), where trans[14]dien is meso-5,7,7,12,14,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene, was obtained by the reaction of [Cu(trans[14]dien)](ClO(4))(2) and [(C(2)H(5))(2)...

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Autores principales: He, Lin-Xin, Zou, Li-Ke, Xie, Bin, Xiang, Yang-Guang, Feng, Jian-Shen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983923/
https://www.ncbi.nlm.nih.gov/pubmed/21580524
http://dx.doi.org/10.1107/S1600536810009815
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author He, Lin-Xin
Zou, Li-Ke
Xie, Bin
Xiang, Yang-Guang
Feng, Jian-Shen
author_facet He, Lin-Xin
Zou, Li-Ke
Xie, Bin
Xiang, Yang-Guang
Feng, Jian-Shen
author_sort He, Lin-Xin
collection PubMed
description The title compound, [Cu(C(16)H(32)N(4))](C(14)H(14)O(2)PS(2))(2) or [Cu(trans[14]dien)][S(2)P(OC(6)H(4)Me-4)(2)](2), where trans[14]dien is meso-5,7,7,12,14,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene, was obtained by the reaction of [Cu(trans[14]dien)](ClO(4))(2) and [(C(2)H(5))(2)NH](2) [S(2)P(OC(6)H(4)Me-4)(2)](2). The Cu(II) atom lies on a centre of inversion and possesses a relatively undistorted square-planar coordination arrangement with four N atoms of the macrocyclic tetra­mine trans[14]dien [Cu—N = 1.9716 (19) and 2.0075 (19) Å]. The two uncoordinated [(4-MeC(6)H(4)O)(2)PS(2)](−) groups act as counter-ions to balance the charge and inter­act with the [Cu(trans[14]dien)](2+ )complex cation through N—H⋯S hydrogen bonds.
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spelling pubmed-29839232010-12-30 (meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate] He, Lin-Xin Zou, Li-Ke Xie, Bin Xiang, Yang-Guang Feng, Jian-Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(16)H(32)N(4))](C(14)H(14)O(2)PS(2))(2) or [Cu(trans[14]dien)][S(2)P(OC(6)H(4)Me-4)(2)](2), where trans[14]dien is meso-5,7,7,12,14,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene, was obtained by the reaction of [Cu(trans[14]dien)](ClO(4))(2) and [(C(2)H(5))(2)NH](2) [S(2)P(OC(6)H(4)Me-4)(2)](2). The Cu(II) atom lies on a centre of inversion and possesses a relatively undistorted square-planar coordination arrangement with four N atoms of the macrocyclic tetra­mine trans[14]dien [Cu—N = 1.9716 (19) and 2.0075 (19) Å]. The two uncoordinated [(4-MeC(6)H(4)O)(2)PS(2)](−) groups act as counter-ions to balance the charge and inter­act with the [Cu(trans[14]dien)](2+ )complex cation through N—H⋯S hydrogen bonds. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983923/ /pubmed/21580524 http://dx.doi.org/10.1107/S1600536810009815 Text en © He et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
He, Lin-Xin
Zou, Li-Ke
Xie, Bin
Xiang, Yang-Guang
Feng, Jian-Shen
(meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]
title (meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]
title_full (meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]
title_fullStr (meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]
title_full_unstemmed (meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]
title_short (meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(II) bis­[O,O′-bis­(4-methyl­phen­yl) dithio­phosphate]
title_sort (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)copper(ii) bis­[o,o′-bis­(4-methyl­phen­yl) dithio­phosphate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983923/
https://www.ncbi.nlm.nih.gov/pubmed/21580524
http://dx.doi.org/10.1107/S1600536810009815
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