Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)

In the title compound, [Zn(C(9)H(8)N(3)O(6)S(3))(2)(C(10)H(8)N(2))(2)], the central Zn(II) ion, situated on a center of inversion, adopts an octa­hedral geometry coordinated by four O atoms from two carboxyl­ate groups and two carboxylic groups of two symmetry-related TTTA ligands and two N atoms fr...

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Detalles Bibliográficos
Autores principales: Wang, Suna, Yang, Yan, Li, Dacheng, Dou, Jianmin, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983928/
https://www.ncbi.nlm.nih.gov/pubmed/21580483
http://dx.doi.org/10.1107/S160053681000735X
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author Wang, Suna
Yang, Yan
Li, Dacheng
Dou, Jianmin
Wang, Daqi
author_facet Wang, Suna
Yang, Yan
Li, Dacheng
Dou, Jianmin
Wang, Daqi
author_sort Wang, Suna
collection PubMed
description In the title compound, [Zn(C(9)H(8)N(3)O(6)S(3))(2)(C(10)H(8)N(2))(2)], the central Zn(II) ion, situated on a center of inversion, adopts an octa­hedral geometry coordinated by four O atoms from two carboxyl­ate groups and two carboxylic groups of two symmetry-related TTTA ligands and two N atoms from two bpy mol­ecules {TTTA is 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanedi­yl)]triacetic acid and bpy is 4,4′-bipyridine}. These mononuclear units are connected through complementary O—H⋯X hydrogen bonds, as well as through weak C—H⋯X (X = O and N) inter­actions, resulting in a three-dimensional supra­molecular architecture.
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spelling pubmed-29839282010-12-30 Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II) Wang, Suna Yang, Yan Li, Dacheng Dou, Jianmin Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(9)H(8)N(3)O(6)S(3))(2)(C(10)H(8)N(2))(2)], the central Zn(II) ion, situated on a center of inversion, adopts an octa­hedral geometry coordinated by four O atoms from two carboxyl­ate groups and two carboxylic groups of two symmetry-related TTTA ligands and two N atoms from two bpy mol­ecules {TTTA is 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanedi­yl)]triacetic acid and bpy is 4,4′-bipyridine}. These mononuclear units are connected through complementary O—H⋯X hydrogen bonds, as well as through weak C—H⋯X (X = O and N) inter­actions, resulting in a three-dimensional supra­molecular architecture. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983928/ /pubmed/21580483 http://dx.doi.org/10.1107/S160053681000735X Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Suna
Yang, Yan
Li, Dacheng
Dou, Jianmin
Wang, Daqi
Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)
title Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)
title_full Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)
title_fullStr Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)
title_full_unstemmed Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)
title_short Bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(II)
title_sort bis(4,4′-bipyrid­yl)bis{2-[4,6-bis­(carboxy­methyl­sulfan­yl)-1,3,5-triazin-2-ylsulfan­yl]acetato}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983928/
https://www.ncbi.nlm.nih.gov/pubmed/21580483
http://dx.doi.org/10.1107/S160053681000735X
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