4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate

In the title compound, (C(10)H(9)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O or (bpyH)[Fe(pydc)(2)]·4H(2)O, the asymmetric unit contains an [Fe(pydc)(2)](−) (pydcH(2)= pyridine-2,6-dicarboxylic acid) anion, a protonated 4,4′-bipyridine as a counter-ion, (bpyH)(+), and four uncoordinated water mol­ecules. The...

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Detalles Bibliográficos
Autores principales: Soleimannejad, Janet, Aghabozorg, Hossein, Sheshmani, Shabnam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983936/
https://www.ncbi.nlm.nih.gov/pubmed/21580510
http://dx.doi.org/10.1107/S1600536810008597
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author Soleimannejad, Janet
Aghabozorg, Hossein
Sheshmani, Shabnam
author_facet Soleimannejad, Janet
Aghabozorg, Hossein
Sheshmani, Shabnam
author_sort Soleimannejad, Janet
collection PubMed
description In the title compound, (C(10)H(9)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O or (bpyH)[Fe(pydc)(2)]·4H(2)O, the asymmetric unit contains an [Fe(pydc)(2)](−) (pydcH(2)= pyridine-2,6-dicarboxylic acid) anion, a protonated 4,4′-bipyridine as a counter-ion, (bpyH)(+), and four uncoordinated water mol­ecules. The anion is a six-coordinate complex with a distorted octa­hedral geometry around the Fe(III )atom. A wide range of non-covalent inter­actions, i.e. O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, ion pairing, C—O⋯π [3.431 (2) Å] and C—H⋯π stacking inter­actions result in the formation of a three-dimensional network structure.
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spelling pubmed-29839362010-12-30 4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate Soleimannejad, Janet Aghabozorg, Hossein Sheshmani, Shabnam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(10)H(9)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O or (bpyH)[Fe(pydc)(2)]·4H(2)O, the asymmetric unit contains an [Fe(pydc)(2)](−) (pydcH(2)= pyridine-2,6-dicarboxylic acid) anion, a protonated 4,4′-bipyridine as a counter-ion, (bpyH)(+), and four uncoordinated water mol­ecules. The anion is a six-coordinate complex with a distorted octa­hedral geometry around the Fe(III )atom. A wide range of non-covalent inter­actions, i.e. O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, ion pairing, C—O⋯π [3.431 (2) Å] and C—H⋯π stacking inter­actions result in the formation of a three-dimensional network structure. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983936/ /pubmed/21580510 http://dx.doi.org/10.1107/S1600536810008597 Text en © Soleimannejad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Soleimannejad, Janet
Aghabozorg, Hossein
Sheshmani, Shabnam
4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate
title 4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate
title_full 4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate
title_fullStr 4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate
title_full_unstemmed 4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate
title_short 4-(4-Pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(III) tetra­hydrate
title_sort 4-(4-pyrid­yl)pyridinium bis­(pyridine-2,6-dicarboxyl­ato)ferrate(iii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983936/
https://www.ncbi.nlm.nih.gov/pubmed/21580510
http://dx.doi.org/10.1107/S1600536810008597
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AT aghabozorghossein 44pyridylpyridiniumbispyridine26dicarboxylatoferrateiiitetrahydrate
AT sheshmanishabnam 44pyridylpyridiniumbispyridine26dicarboxylatoferrateiiitetrahydrate

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