Cargando…

tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate

In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr­oxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O...

Descripción completa

Detalles Bibliográficos
Autores principales: Pinheiro, Alessandra C., de Souza, Marcus V. N., Wardell, Solange M. S. V., Wardell, James L., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983938/
https://www.ncbi.nlm.nih.gov/pubmed/21580790
http://dx.doi.org/10.1107/S1600536810011438
Descripción
Sumario:In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr­oxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups.