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tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate
In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydroxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983938/ https://www.ncbi.nlm.nih.gov/pubmed/21580790 http://dx.doi.org/10.1107/S1600536810011438 |
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author | Pinheiro, Alessandra C. de Souza, Marcus V. N. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. |
author_facet | Pinheiro, Alessandra C. de Souza, Marcus V. N. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. |
author_sort | Pinheiro, Alessandra C. |
collection | PubMed |
description | In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydroxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups. |
format | Text |
id | pubmed-2983938 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29839382010-12-30 tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate Pinheiro, Alessandra C. de Souza, Marcus V. N. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydroxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983938/ /pubmed/21580790 http://dx.doi.org/10.1107/S1600536810011438 Text en © Pinheiro et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pinheiro, Alessandra C. de Souza, Marcus V. N. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
title |
tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
title_full |
tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
title_fullStr |
tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
title_full_unstemmed |
tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
title_short |
tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
title_sort | tert-butyl n-[(s)-1-hydrazinecarbonyl-2-hydroxyethyl]carbamate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983938/ https://www.ncbi.nlm.nih.gov/pubmed/21580790 http://dx.doi.org/10.1107/S1600536810011438 |
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