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tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate

In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr­oxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O...

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Detalles Bibliográficos
Autores principales: Pinheiro, Alessandra C., de Souza, Marcus V. N., Wardell, Solange M. S. V., Wardell, James L., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983938/
https://www.ncbi.nlm.nih.gov/pubmed/21580790
http://dx.doi.org/10.1107/S1600536810011438
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author Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Wardell, Solange M. S. V.
Wardell, James L.
Tiekink, Edward R. T.
author_facet Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Wardell, Solange M. S. V.
Wardell, James L.
Tiekink, Edward R. T.
author_sort Pinheiro, Alessandra C.
collection PubMed
description In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr­oxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups.
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spelling pubmed-29839382010-12-30 tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate Pinheiro, Alessandra C. de Souza, Marcus V. N. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr­oxy group forms an O—H⋯N(a) (a = amine) hydrogen bond and each of the four N—H atoms forms an N—H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983938/ /pubmed/21580790 http://dx.doi.org/10.1107/S1600536810011438 Text en © Pinheiro et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Wardell, Solange M. S. V.
Wardell, James L.
Tiekink, Edward R. T.
tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
title tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
title_full tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
title_fullStr tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
title_full_unstemmed tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
title_short tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
title_sort tert-butyl n-[(s)-1-hydrazinecarbonyl-2-hydroxy­ethyl]carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983938/
https://www.ncbi.nlm.nih.gov/pubmed/21580790
http://dx.doi.org/10.1107/S1600536810011438
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