(E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol

The title Schiff base compound, C(14)H(12)BrClN(2)O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intra­molecular O—H⋯N hydrogen bond forms a six-memb...

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Detalles Bibliográficos
Autores principales: Bahron, Hadariah, Bakar, Siti Najihah Abu, Kassim, Karimah, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983940/
https://www.ncbi.nlm.nih.gov/pubmed/21580701
http://dx.doi.org/10.1107/S1600536810009773
Descripción
Sumario:The title Schiff base compound, C(14)H(12)BrClN(2)O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, mol­ecules are linked into chains along [010] via N—H⋯O hydrogen bonds. The presence of π–π inter­actions [centroid–centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure.

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