(E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol

The title Schiff base compound, C(14)H(12)BrClN(2)O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intra­molecular O—H⋯N hydrogen bond forms a six-memb...

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Autores principales: Bahron, Hadariah, Bakar, Siti Najihah Abu, Kassim, Karimah, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983940/
https://www.ncbi.nlm.nih.gov/pubmed/21580701
http://dx.doi.org/10.1107/S1600536810009773
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author Bahron, Hadariah
Bakar, Siti Najihah Abu
Kassim, Karimah
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Bahron, Hadariah
Bakar, Siti Najihah Abu
Kassim, Karimah
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Bahron, Hadariah
collection PubMed
description The title Schiff base compound, C(14)H(12)BrClN(2)O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, mol­ecules are linked into chains along [010] via N—H⋯O hydrogen bonds. The presence of π–π inter­actions [centroid–centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure.
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spelling pubmed-29839402010-12-30 (E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol Bahron, Hadariah Bakar, Siti Najihah Abu Kassim, Karimah Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(14)H(12)BrClN(2)O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, mol­ecules are linked into chains along [010] via N—H⋯O hydrogen bonds. The presence of π–π inter­actions [centroid–centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983940/ /pubmed/21580701 http://dx.doi.org/10.1107/S1600536810009773 Text en © Bahron et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bahron, Hadariah
Bakar, Siti Najihah Abu
Kassim, Karimah
Yeap, Chin Sing
Fun, Hoong-Kun
(E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
title (E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
title_full (E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
title_fullStr (E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
title_full_unstemmed (E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
title_short (E)-2-[1-(3-Amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
title_sort (e)-2-[1-(3-amino-4-chloro­phenyl­imino)eth­yl]-4-bromo­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983940/
https://www.ncbi.nlm.nih.gov/pubmed/21580701
http://dx.doi.org/10.1107/S1600536810009773
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