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(8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone

In the title compound, C(19)H(14)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the b...

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Autores principales: Mitsui, Ryosuke, Nagasawa, Atsushi, Watanabe, Shoji, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983951/
https://www.ncbi.nlm.nih.gov/pubmed/21580693
http://dx.doi.org/10.1107/S1600536810009463
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author Mitsui, Ryosuke
Nagasawa, Atsushi
Watanabe, Shoji
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Mitsui, Ryosuke
Nagasawa, Atsushi
Watanabe, Shoji
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Mitsui, Ryosuke
collection PubMed
description In the title compound, C(19)H(14)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 75.73 (15)° versus 2.33 (17)°. In the crystal structure, a π–π inter­action is formed between naphthalene ring systems, with a centroid–centroid distance of 3.8363 (14) Å and a lateral offset of 1.606 Å. Inter­molecular C—H⋯Br and C—H⋯O hydrogen bonds and a C—H⋯π contact are present in the crystal structure.
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spelling pubmed-29839512010-12-30 (8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone Mitsui, Ryosuke Nagasawa, Atsushi Watanabe, Shoji Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(14)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 75.73 (15)° versus 2.33 (17)°. In the crystal structure, a π–π inter­action is formed between naphthalene ring systems, with a centroid–centroid distance of 3.8363 (14) Å and a lateral offset of 1.606 Å. Inter­molecular C—H⋯Br and C—H⋯O hydrogen bonds and a C—H⋯π contact are present in the crystal structure. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983951/ /pubmed/21580693 http://dx.doi.org/10.1107/S1600536810009463 Text en © Mitsui et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mitsui, Ryosuke
Nagasawa, Atsushi
Watanabe, Shoji
Okamoto, Akiko
Yonezawa, Noriyuki
(8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
title (8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
title_full (8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
title_fullStr (8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
title_full_unstemmed (8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
title_short (8-Bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
title_sort (8-bromo-2,7-dimeth­oxy-1-naphth­yl)(4-chloro­phenyl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983951/
https://www.ncbi.nlm.nih.gov/pubmed/21580693
http://dx.doi.org/10.1107/S1600536810009463
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