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1,4-Diazoniabicyclo[2.2.2]octane tetrachloroiodate(III) chloride
In the title compound, C(6)H(14)N(2) (2+)·Cl(4)I(−)·Cl(−), the dication and the anions lie on special positions. The dication has mm2 symmetry with two bonded C atoms and the two N atoms located on a crystallographic mirror plane parallel to bc, and with a mirror plane parallel to ab passing through...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983961/ https://www.ncbi.nlm.nih.gov/pubmed/21580627 http://dx.doi.org/10.1107/S1600536810007865 |
Sumario: | In the title compound, C(6)H(14)N(2) (2+)·Cl(4)I(−)·Cl(−), the dication and the anions lie on special positions. The dication has mm2 symmetry with two bonded C atoms and the two N atoms located on a crystallographic mirror plane parallel to bc, and with a mirror plane parallel to ab passing through the mid points of the three C—C bonds. In the square-planar Cl(4)I(−) anion, two Cl atoms and the I atom are located on the mm2 axis; the other two Cl atoms are disordered over two postions of equal occupancy (0.25) across the mirror parallel to the ab plane. The Cl(−) anion is located on the mm2 axis. The crystal structure is stabilized by intermolecular N—H⋯Cl hydrogen bonds. |
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