1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride

In the title compound, C(6)H(14)N(2) (2+)·Cl(4)I(−)·Cl(−), the dication and the anions lie on special positions. The dication has mm2 symmetry with two bonded C atoms and the two N atoms located on a crystallographic mirror plane parallel to bc, and with a mirror plane parallel to ab passing through...

Descripción completa

Detalles Bibliográficos
Autor principal: Chen, Li-Zhuang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983961/
https://www.ncbi.nlm.nih.gov/pubmed/21580627
http://dx.doi.org/10.1107/S1600536810007865
_version_ 1782192000387252224
author Chen, Li-Zhuang
author_facet Chen, Li-Zhuang
author_sort Chen, Li-Zhuang
collection PubMed
description In the title compound, C(6)H(14)N(2) (2+)·Cl(4)I(−)·Cl(−), the dication and the anions lie on special positions. The dication has mm2 symmetry with two bonded C atoms and the two N atoms located on a crystallographic mirror plane parallel to bc, and with a mirror plane parallel to ab passing through the mid points of the three C—C bonds. In the square-planar Cl(4)I(−) anion, two Cl atoms and the I atom are located on the mm2 axis; the other two Cl atoms are disordered over two postions of equal occupancy (0.25) across the mirror parallel to the ab plane. The Cl(−) anion is located on the mm2 axis. The crystal structure is stabilized by inter­molecular N—H⋯Cl hydrogen bonds.
format Text
id pubmed-2983961
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29839612010-12-30 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride Chen, Li-Zhuang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(14)N(2) (2+)·Cl(4)I(−)·Cl(−), the dication and the anions lie on special positions. The dication has mm2 symmetry with two bonded C atoms and the two N atoms located on a crystallographic mirror plane parallel to bc, and with a mirror plane parallel to ab passing through the mid points of the three C—C bonds. In the square-planar Cl(4)I(−) anion, two Cl atoms and the I atom are located on the mm2 axis; the other two Cl atoms are disordered over two postions of equal occupancy (0.25) across the mirror parallel to the ab plane. The Cl(−) anion is located on the mm2 axis. The crystal structure is stabilized by inter­molecular N—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-03-10 /pmc/articles/PMC2983961/ /pubmed/21580627 http://dx.doi.org/10.1107/S1600536810007865 Text en © Li-Zhuang Chen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Li-Zhuang
1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride
title 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride
title_full 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride
title_fullStr 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride
title_full_unstemmed 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride
title_short 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(III) chloride
title_sort 1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloroiodate(iii) chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983961/
https://www.ncbi.nlm.nih.gov/pubmed/21580627
http://dx.doi.org/10.1107/S1600536810007865
work_keys_str_mv AT chenlizhuang 14diazoniabicyclo222octanetetrachloroiodateiiichloride

Ejemplares similares