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Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II)
The title compound, (C(12)H(16)N(2))(2)[PbBr(6)], is an organic–inorganic salt, with two doubly protonated N-(1-naphthyl)ethylenediammonium cations and one octahedral hexabromidoplumbate(II) anion. The Pb(II) atom is located on a centre of inversion. The crystal structure consists of alternating...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983965/ https://www.ncbi.nlm.nih.gov/pubmed/21580515 http://dx.doi.org/10.1107/S1600536810008901 |
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| author | Chen, Yao Zheng, Ying-Ying Wu, Gang Wang, Mang Chen, Hong-Zheng Yang, Hui |
| author_facet | Chen, Yao Zheng, Ying-Ying Wu, Gang Wang, Mang Chen, Hong-Zheng Yang, Hui |
| author_sort | Chen, Yao |
| collection | PubMed |
| description | The title compound, (C(12)H(16)N(2))(2)[PbBr(6)], is an organic–inorganic salt, with two doubly protonated N-(1-naphthyl)ethylenediammonium cations and one octahedral hexabromidoplumbate(II) anion. The Pb(II) atom is located on a centre of inversion. The crystal structure consists of alternating inorganic and organic layers parallel to the bc plane. Face-to-face aromatic stacking interactions [centroid–centroid distance = 3.505 (5) Å] occur between parallel naphthalene systems in the organic layers, and N—H⋯Br hydrogen bonds between the cations and anions stabilize the crystal structure. |
| format | Text |
| id | pubmed-2983965 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29839652010-12-30 Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) Chen, Yao Zheng, Ying-Ying Wu, Gang Wang, Mang Chen, Hong-Zheng Yang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(12)H(16)N(2))(2)[PbBr(6)], is an organic–inorganic salt, with two doubly protonated N-(1-naphthyl)ethylenediammonium cations and one octahedral hexabromidoplumbate(II) anion. The Pb(II) atom is located on a centre of inversion. The crystal structure consists of alternating inorganic and organic layers parallel to the bc plane. Face-to-face aromatic stacking interactions [centroid–centroid distance = 3.505 (5) Å] occur between parallel naphthalene systems in the organic layers, and N—H⋯Br hydrogen bonds between the cations and anions stabilize the crystal structure. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983965/ /pubmed/21580515 http://dx.doi.org/10.1107/S1600536810008901 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Yao Zheng, Ying-Ying Wu, Gang Wang, Mang Chen, Hong-Zheng Yang, Hui Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) |
| title | Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) |
| title_full | Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) |
| title_fullStr | Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) |
| title_full_unstemmed | Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) |
| title_short | Bis[N-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(II) |
| title_sort | bis[n-(1-naphthyl)ethylenediammonium] hexabromidoplumbate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983965/ https://www.ncbi.nlm.nih.gov/pubmed/21580515 http://dx.doi.org/10.1107/S1600536810008901 |
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