[(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.54 (2)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983967/
https://www.ncbi.nlm.nih.gov/pubmed/21580525
http://dx.doi.org/10.1107/S1600536810009906
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.54 (2)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol­ecules are arranged into supra­molecular chains along the b axis mediated by C—H⋯O inter­actions.
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spelling pubmed-29839672010-12-30 [(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.54 (2)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol­ecules are arranged into supra­molecular chains along the b axis mediated by C—H⋯O inter­actions. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983967/ /pubmed/21580525 http://dx.doi.org/10.1107/S1600536810009906 Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title [(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full [(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_fullStr [(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_short [(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_sort [(z)-o-isopropyl n-phenyl­thio­car­bam­ato-κs](tricyclo­hexyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983967/
https://www.ncbi.nlm.nih.gov/pubmed/21580525
http://dx.doi.org/10.1107/S1600536810009906
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AT tiekinkedwardrt zoisopropylnphenylthiocarbamatokstricyclohexylphosphinekpgoldi

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