[2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate

In the title hydrated molecular salt, C(12)H(19)N(2)Se(+)·Br(−)·H(2)O, the two independent bromide anions lie on a twofold rotation axis. Strong intra­molecular N→Se inter­actions [2.185 (3) and 2.181 (3) Å] are established by both N atoms of the organic group in the cation, in trans positions to ea...

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Detalles Bibliográficos
Autores principales: Varga, Richard A., Kulcsar, Monica, Silvestru, Anca
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983970/
https://www.ncbi.nlm.nih.gov/pubmed/21580615
http://dx.doi.org/10.1107/S1600536810008019
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author Varga, Richard A.
Kulcsar, Monica
Silvestru, Anca
author_facet Varga, Richard A.
Kulcsar, Monica
Silvestru, Anca
author_sort Varga, Richard A.
collection PubMed
description In the title hydrated molecular salt, C(12)H(19)N(2)Se(+)·Br(−)·H(2)O, the two independent bromide anions lie on a twofold rotation axis. Strong intra­molecular N→Se inter­actions [2.185 (3) and 2.181 (3) Å] are established by both N atoms of the organic group in the cation, in trans positions to each other, with an N—Se—N angle of 161.6 (1)°, resulting in a T-shaped (C,N,N′)Se core. In the crystal, dimeric associations are formed by Br⋯Se [3.662 (2) Å] and Br⋯H inter­actions [2.56 (6) and 2.63 (7) Å] involving two bromide anions, two cations and two water mol­ecules.
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spelling pubmed-29839702010-12-30 [2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate Varga, Richard A. Kulcsar, Monica Silvestru, Anca Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated molecular salt, C(12)H(19)N(2)Se(+)·Br(−)·H(2)O, the two independent bromide anions lie on a twofold rotation axis. Strong intra­molecular N→Se inter­actions [2.185 (3) and 2.181 (3) Å] are established by both N atoms of the organic group in the cation, in trans positions to each other, with an N—Se—N angle of 161.6 (1)°, resulting in a T-shaped (C,N,N′)Se core. In the crystal, dimeric associations are formed by Br⋯Se [3.662 (2) Å] and Br⋯H inter­actions [2.56 (6) and 2.63 (7) Å] involving two bromide anions, two cations and two water mol­ecules. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983970/ /pubmed/21580615 http://dx.doi.org/10.1107/S1600536810008019 Text en © Varga et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Varga, Richard A.
Kulcsar, Monica
Silvestru, Anca
[2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
title [2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
title_full [2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
title_fullStr [2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
title_full_unstemmed [2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
title_short [2,6-Bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
title_sort [2,6-bis(dimethyl­amino­meth­yl)phen­yl]selenium bromide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983970/
https://www.ncbi.nlm.nih.gov/pubmed/21580615
http://dx.doi.org/10.1107/S1600536810008019
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AT kulcsarmonica 26bisdimethylaminomethylphenylseleniumbromidemonohydrate
AT silvestruanca 26bisdimethylaminomethylphenylseleniumbromidemonohydrate

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