Bis(ethyl­enediammonium) tetra­deca­borate

The title compound, 2C(2)H(10)N(2) (2+)·B(14)O(20)(OH)(6) (4−), consists of a centrosymmetric tetra­deca­borate anion and two ethyl­enediammonium cations. The anions are inter­connected through strong O—H⋯O hydrogen bonds into a three-dimensional supra­molecular network with channels along [100], [0...

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Detalles Bibliográficos
Autores principales: Wang, Guo-Ming, Wang, Pei, Li, Zeng-Xin, Li, Hui, Liu, Hui-Luan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983971/
https://www.ncbi.nlm.nih.gov/pubmed/21580636
http://dx.doi.org/10.1107/S1600536810008494
Descripción
Sumario:The title compound, 2C(2)H(10)N(2) (2+)·B(14)O(20)(OH)(6) (4−), consists of a centrosymmetric tetra­deca­borate anion and two ethyl­enediammonium cations. The anions are inter­connected through strong O—H⋯O hydrogen bonds into a three-dimensional supra­molecular network with channels along [100], [010], [001] and [111]. The diprotonated cations reside in the channels and inter­act with the inorganic framework by extensive N—H⋯O hydrogen bonds.

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