Cargando…
Bis(ethylenediammonium) tetradecaborate
The title compound, 2C(2)H(10)N(2) (2+)·B(14)O(20)(OH)(6) (4−), consists of a centrosymmetric tetradecaborate anion and two ethylenediammonium cations. The anions are interconnected through strong O—H⋯O hydrogen bonds into a three-dimensional supramolecular network with channels along [100], [0...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983971/ https://www.ncbi.nlm.nih.gov/pubmed/21580636 http://dx.doi.org/10.1107/S1600536810008494 |
_version_ | 1782192002945777664 |
---|---|
author | Wang, Guo-Ming Wang, Pei Li, Zeng-Xin Li, Hui Liu, Hui-Luan |
author_facet | Wang, Guo-Ming Wang, Pei Li, Zeng-Xin Li, Hui Liu, Hui-Luan |
author_sort | Wang, Guo-Ming |
collection | PubMed |
description | The title compound, 2C(2)H(10)N(2) (2+)·B(14)O(20)(OH)(6) (4−), consists of a centrosymmetric tetradecaborate anion and two ethylenediammonium cations. The anions are interconnected through strong O—H⋯O hydrogen bonds into a three-dimensional supramolecular network with channels along [100], [010], [001] and [111]. The diprotonated cations reside in the channels and interact with the inorganic framework by extensive N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2983971 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29839712010-12-30 Bis(ethylenediammonium) tetradecaborate Wang, Guo-Ming Wang, Pei Li, Zeng-Xin Li, Hui Liu, Hui-Luan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 2C(2)H(10)N(2) (2+)·B(14)O(20)(OH)(6) (4−), consists of a centrosymmetric tetradecaborate anion and two ethylenediammonium cations. The anions are interconnected through strong O—H⋯O hydrogen bonds into a three-dimensional supramolecular network with channels along [100], [010], [001] and [111]. The diprotonated cations reside in the channels and interact with the inorganic framework by extensive N—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983971/ /pubmed/21580636 http://dx.doi.org/10.1107/S1600536810008494 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Guo-Ming Wang, Pei Li, Zeng-Xin Li, Hui Liu, Hui-Luan Bis(ethylenediammonium) tetradecaborate |
title | Bis(ethylenediammonium) tetradecaborate |
title_full | Bis(ethylenediammonium) tetradecaborate |
title_fullStr | Bis(ethylenediammonium) tetradecaborate |
title_full_unstemmed | Bis(ethylenediammonium) tetradecaborate |
title_short | Bis(ethylenediammonium) tetradecaborate |
title_sort | bis(ethylenediammonium) tetradecaborate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983971/ https://www.ncbi.nlm.nih.gov/pubmed/21580636 http://dx.doi.org/10.1107/S1600536810008494 |
work_keys_str_mv | AT wangguoming bisethylenediammoniumtetradecaborate AT wangpei bisethylenediammoniumtetradecaborate AT lizengxin bisethylenediammoniumtetradecaborate AT lihui bisethylenediammoniumtetradecaborate AT liuhuiluan bisethylenediammoniumtetradecaborate |