2-Amino-5-chloro­pyridinium trifluoro­acetate

The asymmetric unit of the title salt, C(5)H(6)ClN(2) (+)·C(2)F(3)O(2) (−), contains two independent 2-amino-5-chloro­pyridinium cations and two independent trifluoro­acetate anions. The F atoms of both anions are disordered over two sets of positions, with occupancy ratios of 0.672 (12):0.328 (12)...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983973/
https://www.ncbi.nlm.nih.gov/pubmed/21580623
http://dx.doi.org/10.1107/S1600536810008196
Descripción
Sumario:The asymmetric unit of the title salt, C(5)H(6)ClN(2) (+)·C(2)F(3)O(2) (−), contains two independent 2-amino-5-chloro­pyridinium cations and two independent trifluoro­acetate anions. The F atoms of both anions are disordered over two sets of positions, with occupancy ratios of 0.672 (12):0.328 (12) and 0.587 (15):0.413 (15). In the crystal, the cations and anions are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (001).

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