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Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate]
In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octahedral geometry and is chelated by two kinds of l-tartrate ligands through the hydroxy and carboxylate groups and coordinated by one unchelat...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983975/ https://www.ncbi.nlm.nih.gov/pubmed/21580485 http://dx.doi.org/10.1107/S1600536810007543 |
Sumario: | In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octahedral geometry and is chelated by two kinds of l-tartrate ligands through the hydroxy and carboxylate groups and coordinated by one unchelating carboxylate O atom and one water molecule. In the crystal, the l-tartrate ligands link the Zn(II) atoms, forming a two-dimensional coordination layer; these layers are futher linked into a three-dimensional supramolecular network by O—H⋯O hydrogen bonds between the two-dimensional coordination layers and the uncoordinated water molecules. The latter are equally disordered over two positions. |
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