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Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]

In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octa­hedral geometry and is chelated by two kinds of l-tartrate ligands through the hydr­oxy and carboxyl­ate groups and coordinated by one unchelat...

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Detalles Bibliográficos
Autores principales: Liu, Hou-Ting, Lu, Jing, Wang, Da-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983975/
https://www.ncbi.nlm.nih.gov/pubmed/21580485
http://dx.doi.org/10.1107/S1600536810007543
Descripción
Sumario:In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octa­hedral geometry and is chelated by two kinds of l-tartrate ligands through the hydr­oxy and carboxyl­ate groups and coordinated by one unchelating carboxyl­ate O atom and one water mol­ecule. In the crystal, the l-tartrate ligands link the Zn(II) atoms, forming a two-dimensional coordination layer; these layers are futher linked into a three-dimensional supra­molecular network by O—H⋯O hydrogen bonds between the two-dimensional coordin­ation layers and the uncoordinated water mol­ecules. The latter are equally disordered over two positions.