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Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate]
In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octahedral geometry and is chelated by two kinds of l-tartrate ligands through the hydroxy and carboxylate groups and coordinated by one unchelat...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983975/ https://www.ncbi.nlm.nih.gov/pubmed/21580485 http://dx.doi.org/10.1107/S1600536810007543 |
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author | Liu, Hou-Ting Lu, Jing Wang, Da-Qi |
author_facet | Liu, Hou-Ting Lu, Jing Wang, Da-Qi |
author_sort | Liu, Hou-Ting |
collection | PubMed |
description | In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octahedral geometry and is chelated by two kinds of l-tartrate ligands through the hydroxy and carboxylate groups and coordinated by one unchelating carboxylate O atom and one water molecule. In the crystal, the l-tartrate ligands link the Zn(II) atoms, forming a two-dimensional coordination layer; these layers are futher linked into a three-dimensional supramolecular network by O—H⋯O hydrogen bonds between the two-dimensional coordination layers and the uncoordinated water molecules. The latter are equally disordered over two positions. |
format | Text |
id | pubmed-2983975 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29839752010-12-30 Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] Liu, Hou-Ting Lu, Jing Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octahedral geometry and is chelated by two kinds of l-tartrate ligands through the hydroxy and carboxylate groups and coordinated by one unchelating carboxylate O atom and one water molecule. In the crystal, the l-tartrate ligands link the Zn(II) atoms, forming a two-dimensional coordination layer; these layers are futher linked into a three-dimensional supramolecular network by O—H⋯O hydrogen bonds between the two-dimensional coordination layers and the uncoordinated water molecules. The latter are equally disordered over two positions. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983975/ /pubmed/21580485 http://dx.doi.org/10.1107/S1600536810007543 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Hou-Ting Lu, Jing Wang, Da-Qi Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] |
title | Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] |
title_full | Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] |
title_fullStr | Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] |
title_full_unstemmed | Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] |
title_short | Poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetrahydrate] |
title_sort | poly[[diaqua(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(ii)] tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983975/ https://www.ncbi.nlm.nih.gov/pubmed/21580485 http://dx.doi.org/10.1107/S1600536810007543 |
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