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Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]

In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octa­hedral geometry and is chelated by two kinds of l-tartrate ligands through the hydr­oxy and carboxyl­ate groups and coordinated by one unchelat...

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Detalles Bibliográficos
Autores principales: Liu, Hou-Ting, Lu, Jing, Wang, Da-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983975/
https://www.ncbi.nlm.nih.gov/pubmed/21580485
http://dx.doi.org/10.1107/S1600536810007543
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author Liu, Hou-Ting
Lu, Jing
Wang, Da-Qi
author_facet Liu, Hou-Ting
Lu, Jing
Wang, Da-Qi
author_sort Liu, Hou-Ting
collection PubMed
description In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octa­hedral geometry and is chelated by two kinds of l-tartrate ligands through the hydr­oxy and carboxyl­ate groups and coordinated by one unchelating carboxyl­ate O atom and one water mol­ecule. In the crystal, the l-tartrate ligands link the Zn(II) atoms, forming a two-dimensional coordination layer; these layers are futher linked into a three-dimensional supra­molecular network by O—H⋯O hydrogen bonds between the two-dimensional coordin­ation layers and the uncoordinated water mol­ecules. The latter are equally disordered over two positions.
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spelling pubmed-29839752010-12-30 Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate] Liu, Hou-Ting Lu, Jing Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(4)H(4)O(6))(H(2)O)]·2H(2)O}(n), the l-tartrate ligands adopt μ(4)- and μ(2)-coordination modes. The Zn(II) atom adopts an octa­hedral geometry and is chelated by two kinds of l-tartrate ligands through the hydr­oxy and carboxyl­ate groups and coordinated by one unchelating carboxyl­ate O atom and one water mol­ecule. In the crystal, the l-tartrate ligands link the Zn(II) atoms, forming a two-dimensional coordination layer; these layers are futher linked into a three-dimensional supra­molecular network by O—H⋯O hydrogen bonds between the two-dimensional coordin­ation layers and the uncoordinated water mol­ecules. The latter are equally disordered over two positions. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983975/ /pubmed/21580485 http://dx.doi.org/10.1107/S1600536810007543 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Hou-Ting
Lu, Jing
Wang, Da-Qi
Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]
title Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]
title_full Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]
title_fullStr Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]
title_full_unstemmed Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]
title_short Poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(II)] tetra­hydrate]
title_sort poly[[diaqua­(μ(4)-l-tartrato)(μ(2)-l-tartrato)dizinc(ii)] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983975/
https://www.ncbi.nlm.nih.gov/pubmed/21580485
http://dx.doi.org/10.1107/S1600536810007543
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