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4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide

In the title moleclue, C(13)H(10)N(4)O(3), the methyl­idene–hydrazide [–C(=O)—N—N=C–] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the...

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Autores principales: Ahmad, Tanveer, Zia-ur-Rehman, Muhammad, Siddiqui, Hamid Latif, Mahmud, Shahid, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983976/
https://www.ncbi.nlm.nih.gov/pubmed/21580774
http://dx.doi.org/10.1107/S1600536810011244
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author Ahmad, Tanveer
Zia-ur-Rehman, Muhammad
Siddiqui, Hamid Latif
Mahmud, Shahid
Parvez, Masood
author_facet Ahmad, Tanveer
Zia-ur-Rehman, Muhammad
Siddiqui, Hamid Latif
Mahmud, Shahid
Parvez, Masood
author_sort Ahmad, Tanveer
collection PubMed
description In the title moleclue, C(13)H(10)N(4)O(3), the methyl­idene–hydrazide [–C(=O)—N—N=C–] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the methyl­idene–hydrazide fragment. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link mol­ecules into chains along the b axis. Additional stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds. The O atoms of the nitro group are disordered over two sets of sites of equal occupancy.
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spelling pubmed-29839762010-12-30 4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Mahmud, Shahid Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title moleclue, C(13)H(10)N(4)O(3), the methyl­idene–hydrazide [–C(=O)—N—N=C–] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the methyl­idene–hydrazide fragment. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link mol­ecules into chains along the b axis. Additional stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds. The O atoms of the nitro group are disordered over two sets of sites of equal occupancy. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983976/ /pubmed/21580774 http://dx.doi.org/10.1107/S1600536810011244 Text en © Ahmad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmad, Tanveer
Zia-ur-Rehman, Muhammad
Siddiqui, Hamid Latif
Mahmud, Shahid
Parvez, Masood
4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide
title 4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide
title_full 4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide
title_fullStr 4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide
title_full_unstemmed 4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide
title_short 4-Nitro-N′-[(E)-3-pyridylmethyl­idene]benzohydrazide
title_sort 4-nitro-n′-[(e)-3-pyridylmethyl­idene]benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983976/
https://www.ncbi.nlm.nih.gov/pubmed/21580774
http://dx.doi.org/10.1107/S1600536810011244
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