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4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide
In the title moleclue, C(13)H(10)N(4)O(3), the methylidene–hydrazide [–C(=O)—N—N=C–] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983976/ https://www.ncbi.nlm.nih.gov/pubmed/21580774 http://dx.doi.org/10.1107/S1600536810011244 |
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author | Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Mahmud, Shahid Parvez, Masood |
author_facet | Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Mahmud, Shahid Parvez, Masood |
author_sort | Ahmad, Tanveer |
collection | PubMed |
description | In the title moleclue, C(13)H(10)N(4)O(3), the methylidene–hydrazide [–C(=O)—N—N=C–] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the methylidene–hydrazide fragment. In the crystal structure, intermolecular N—H⋯N hydrogen bonds link molecules into chains along the b axis. Additional stabilization is provided by weak intermolecular C—H⋯O hydrogen bonds. The O atoms of the nitro group are disordered over two sets of sites of equal occupancy. |
format | Text |
id | pubmed-2983976 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29839762010-12-30 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Mahmud, Shahid Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title moleclue, C(13)H(10)N(4)O(3), the methylidene–hydrazide [–C(=O)—N—N=C–] fragment is essentially planar, with a maximum deviation of 0.0228 (7) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 25.44 (6) and 5.47 (7)°, respectively, with the mean plane of the methylidene–hydrazide fragment. In the crystal structure, intermolecular N—H⋯N hydrogen bonds link molecules into chains along the b axis. Additional stabilization is provided by weak intermolecular C—H⋯O hydrogen bonds. The O atoms of the nitro group are disordered over two sets of sites of equal occupancy. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983976/ /pubmed/21580774 http://dx.doi.org/10.1107/S1600536810011244 Text en © Ahmad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Mahmud, Shahid Parvez, Masood 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide |
title | 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide |
title_full | 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide |
title_fullStr | 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide |
title_full_unstemmed | 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide |
title_short | 4-Nitro-N′-[(E)-3-pyridylmethylidene]benzohydrazide |
title_sort | 4-nitro-n′-[(e)-3-pyridylmethylidene]benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983976/ https://www.ncbi.nlm.nih.gov/pubmed/21580774 http://dx.doi.org/10.1107/S1600536810011244 |
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