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6-Bromo-1,3-di-2-propynyl-1H-imidazo[4,5-b]pyridin-2(3H)-one

The room-temperature reaction of propargyl bromide and 6-bromo-1,3-dihydro­imidazo[4,5-b]pyridin-2-one in dimethyl­formamide yields the title compound, C(12)H(8)BrN(3)O, which features nitro­gen-bound propynyl substituents. The imidazopyridine fused ring is almost planar (r.m.s. deviation = 0.011 Å)...

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Detalles Bibliográficos
Autores principales: Dahmani, S., Haoudi, A., Capet, F., Essassi, El Mokhtar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983980/
https://www.ncbi.nlm.nih.gov/pubmed/21580601
http://dx.doi.org/10.1107/S1600536810007701
Descripción
Sumario:The room-temperature reaction of propargyl bromide and 6-bromo-1,3-dihydro­imidazo[4,5-b]pyridin-2-one in dimethyl­formamide yields the title compound, C(12)H(8)BrN(3)O, which features nitro­gen-bound propynyl substituents. The imidazopyridine fused ring is almost planar (r.m.s. deviation = 0.011 Å); the propynyl chains point in opposite directions relative to the fused ring. One acetyl­enic H atom is hydrogen bonded to the carbonyl O atom of an inversion-related mol­ecule, forming a dimer; adjacent dimers are linked by a second acetyl­ene–pyridine C—H⋯N inter­action, forming a layer motif.