N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine

In the title Schiff base, C(17)H(14)Cl(4)N(2), the atoms of one of the 2,6-dichloro­benzyl­idene units and the central 1,2-diamino­propane grouping are disordered over two sets of sites in a 0.8838 (12):0.1162 (12) ratio. The dihedral angles between the ordered benzene ring and its disordered counte...

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Detalles Bibliográficos
Autores principales: Yeap, Chin Sing, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983987/
https://www.ncbi.nlm.nih.gov/pubmed/21580598
http://dx.doi.org/10.1107/S160053681000766X
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author Yeap, Chin Sing
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Yeap, Chin Sing
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Yeap, Chin Sing
collection PubMed
description In the title Schiff base, C(17)H(14)Cl(4)N(2), the atoms of one of the 2,6-dichloro­benzyl­idene units and the central 1,2-diamino­propane grouping are disordered over two sets of sites in a 0.8838 (12):0.1162 (12) ratio. The dihedral angles between the ordered benzene ring and its disordered counterparts are 57.41 (12) and 54.8 (6)° for the major and minor disorder components, respectively. The crystal studied was a racemic twin, the refined ratio of the twin components being 0.37 (5):0.63 (5).
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spelling pubmed-29839872010-12-30 N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine Yeap, Chin Sing Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base, C(17)H(14)Cl(4)N(2), the atoms of one of the 2,6-dichloro­benzyl­idene units and the central 1,2-diamino­propane grouping are disordered over two sets of sites in a 0.8838 (12):0.1162 (12) ratio. The dihedral angles between the ordered benzene ring and its disordered counterparts are 57.41 (12) and 54.8 (6)° for the major and minor disorder components, respectively. The crystal studied was a racemic twin, the refined ratio of the twin components being 0.37 (5):0.63 (5). International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983987/ /pubmed/21580598 http://dx.doi.org/10.1107/S160053681000766X Text en © Yeap et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yeap, Chin Sing
Hemamalini, Madhukar
Fun, Hoong-Kun
N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
title N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
title_full N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
title_fullStr N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
title_full_unstemmed N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
title_short N,N′-Bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
title_sort n,n′-bis(2,6-dichloro­benzyl­idene)propane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983987/
https://www.ncbi.nlm.nih.gov/pubmed/21580598
http://dx.doi.org/10.1107/S160053681000766X
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