Penta­carbon­yl{3-[(2S)-1-methyl­pyrrolidin-2-yl]pyridine}tungsten(0)

The title compound, [W(C(10)H(14)N(2))(CO)(5)], contains five carbonyl ligands and a nicotine ligand in an octa­hedral arrangement around the tungsten atom. The metal atom shows cis angles in the range 87.30 (16)–94.2 (2)°, and trans angles between 175.2 (2) and 178.1 (4)°. The W—CO bond trans to th...

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Detalles Bibliográficos
Autores principales: Onani, Martin O., Lalancette, Roger A., Muriithi, Naftali T., Nyawade, Eunice A., Kgarebe, Boitumelo V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983989/
https://www.ncbi.nlm.nih.gov/pubmed/21580560
http://dx.doi.org/10.1107/S1600536810010974
Descripción
Sumario:The title compound, [W(C(10)H(14)N(2))(CO)(5)], contains five carbonyl ligands and a nicotine ligand in an octa­hedral arrangement around the tungsten atom. The metal atom shows cis angles in the range 87.30 (16)–94.2 (2)°, and trans angles between 175.2 (2) and 178.1 (4)°. The W—CO bond trans to the pyridine N atom [1.987 (6) Å] is noticeably shorter than the others, which range between 2.036 (3) and 2.064 (3) Å, possibly due to the well-known trans effect. The distance between the W atom and the pyridine N atom is 2.278 (4) Å.

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