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Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0)
The title compound, [W(C(10)H(14)N(2))(CO)(5)], contains five carbonyl ligands and a nicotine ligand in an octahedral arrangement around the tungsten atom. The metal atom shows cis angles in the range 87.30 (16)–94.2 (2)°, and trans angles between 175.2 (2) and 178.1 (4)°. The W—CO bond trans to th...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983989/ https://www.ncbi.nlm.nih.gov/pubmed/21580560 http://dx.doi.org/10.1107/S1600536810010974 |
| _version_ | 1782192007278493696 |
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| author | Onani, Martin O. Lalancette, Roger A. Muriithi, Naftali T. Nyawade, Eunice A. Kgarebe, Boitumelo V. |
| author_facet | Onani, Martin O. Lalancette, Roger A. Muriithi, Naftali T. Nyawade, Eunice A. Kgarebe, Boitumelo V. |
| author_sort | Onani, Martin O. |
| collection | PubMed |
| description | The title compound, [W(C(10)H(14)N(2))(CO)(5)], contains five carbonyl ligands and a nicotine ligand in an octahedral arrangement around the tungsten atom. The metal atom shows cis angles in the range 87.30 (16)–94.2 (2)°, and trans angles between 175.2 (2) and 178.1 (4)°. The W—CO bond trans to the pyridine N atom [1.987 (6) Å] is noticeably shorter than the others, which range between 2.036 (3) and 2.064 (3) Å, possibly due to the well-known trans effect. The distance between the W atom and the pyridine N atom is 2.278 (4) Å. |
| format | Text |
| id | pubmed-2983989 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29839892010-12-30 Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) Onani, Martin O. Lalancette, Roger A. Muriithi, Naftali T. Nyawade, Eunice A. Kgarebe, Boitumelo V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [W(C(10)H(14)N(2))(CO)(5)], contains five carbonyl ligands and a nicotine ligand in an octahedral arrangement around the tungsten atom. The metal atom shows cis angles in the range 87.30 (16)–94.2 (2)°, and trans angles between 175.2 (2) and 178.1 (4)°. The W—CO bond trans to the pyridine N atom [1.987 (6) Å] is noticeably shorter than the others, which range between 2.036 (3) and 2.064 (3) Å, possibly due to the well-known trans effect. The distance between the W atom and the pyridine N atom is 2.278 (4) Å. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983989/ /pubmed/21580560 http://dx.doi.org/10.1107/S1600536810010974 Text en © Onani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Onani, Martin O. Lalancette, Roger A. Muriithi, Naftali T. Nyawade, Eunice A. Kgarebe, Boitumelo V. Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| title | Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| title_full | Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| title_fullStr | Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| title_full_unstemmed | Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| title_short | Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| title_sort | pentacarbonyl{3-[(2s)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983989/ https://www.ncbi.nlm.nih.gov/pubmed/21580560 http://dx.doi.org/10.1107/S1600536810010974 |
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