Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate

The asymmetric unit of the title compound, [Co(C(9)H(12)N(4)O(3))(2)](NO(3))(2)·2H(2)O, consists of a discrete cationic [Co(PLSC)(2)](2+) complex unit [PLSC is 4-(2-carbamoylhydrazin-1-yl­idene)-5-hydroxy­methyl-2-methyl­pyridinium-3-ol­ato], two NO(3) (−) and two water mol­ecules. The two tridentat...

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Detalles Bibliográficos
Autores principales: Vidovic, Dragoslav, Jevtovic, Violeta
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984000/
https://www.ncbi.nlm.nih.gov/pubmed/21580508
http://dx.doi.org/10.1107/S1600536810003570
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author Vidovic, Dragoslav
Jevtovic, Violeta
author_facet Vidovic, Dragoslav
Jevtovic, Violeta
author_sort Vidovic, Dragoslav
collection PubMed
description The asymmetric unit of the title compound, [Co(C(9)H(12)N(4)O(3))(2)](NO(3))(2)·2H(2)O, consists of a discrete cationic [Co(PLSC)(2)](2+) complex unit [PLSC is 4-(2-carbamoylhydrazin-1-yl­idene)-5-hydroxy­methyl-2-methyl­pyridinium-3-ol­ato], two NO(3) (−) and two water mol­ecules. The two tridentate PLSC ligands of the cation are zwitterions related to each other by a non-crystallographic C (2) axis. The Co(II) ion is in a disorted octa­hedral coordination environment. The crystal structure is composed of alternating NO(3)/H(2)O and complex layers supported by extensive C—H⋯O, N—H⋯O and N—H⋯N hydrogen bonding.
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spelling pubmed-29840002010-12-30 Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate Vidovic, Dragoslav Jevtovic, Violeta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(C(9)H(12)N(4)O(3))(2)](NO(3))(2)·2H(2)O, consists of a discrete cationic [Co(PLSC)(2)](2+) complex unit [PLSC is 4-(2-carbamoylhydrazin-1-yl­idene)-5-hydroxy­methyl-2-methyl­pyridinium-3-ol­ato], two NO(3) (−) and two water mol­ecules. The two tridentate PLSC ligands of the cation are zwitterions related to each other by a non-crystallographic C (2) axis. The Co(II) ion is in a disorted octa­hedral coordination environment. The crystal structure is composed of alternating NO(3)/H(2)O and complex layers supported by extensive C—H⋯O, N—H⋯O and N—H⋯N hydrogen bonding. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2984000/ /pubmed/21580508 http://dx.doi.org/10.1107/S1600536810003570 Text en © Vidovic and Jevtovic 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vidovic, Dragoslav
Jevtovic, Violeta
Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate
title Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate
title_full Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate
title_fullStr Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate
title_full_unstemmed Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate
title_short Bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) N (1),O)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κO (3)]cobalt(II) dinitrate dihydrate
title_sort bis[4-(2-carbamoylhydrazin-1-yl­idene-κ(2) n (1),o)-5-hydroxy­methyl-2-methyl­pyridinium-3-olato-κo (3)]cobalt(ii) dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984000/
https://www.ncbi.nlm.nih.gov/pubmed/21580508
http://dx.doi.org/10.1107/S1600536810003570
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AT jevtovicvioleta bis42carbamoylhydrazin1ylidenek2n1o5hydroxymethyl2methylpyridinium3olatoko3cobaltiidinitratedihydrate

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