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Tris{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}trichlorido­erbium(III)

The asymmetric unit of the title compound, [ErCl(3)(C(10)H(17)Cl(3)N(3)O(2)P)(3)], contains two independent mol­ecules. In each mol­ecule, the Er(III) ion is six-coordinated in a slightly distorted octa­hedral ErO(3)Cl(3) geometry with a fac-arrangement of the donor atoms. Intra­molecular N—H⋯Cl hyd...

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Detalles Bibliográficos
Autores principales: Znovjyak, Kateryna O., Ovchynnikov, Vladimir A., Shishkina, Svitlana V., Sliva, Tetyana Yu., Amirkhanov, Vladimir M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984002/
https://www.ncbi.nlm.nih.gov/pubmed/21580536
http://dx.doi.org/10.1107/S1600536810010408
Descripción
Sumario:The asymmetric unit of the title compound, [ErCl(3)(C(10)H(17)Cl(3)N(3)O(2)P)(3)], contains two independent mol­ecules. In each mol­ecule, the Er(III) ion is six-coordinated in a slightly distorted octa­hedral ErO(3)Cl(3) geometry with a fac-arrangement of the donor atoms. Intra­molecular N—H⋯Cl hydrogen bonds influence the mol­ecular conformations. Some of the pyrrolidine fragments in the N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide ligands are disordered over two conformations of equal occupancy. The unusually porous crystal packing exhibits voids of 162, 158 and 13 Å(3 )and short inter­molecular Cl⋯O contacts of 2.876 (3) and 3.022 (4) Å.