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Tris{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}trichloridoerbium(III)
The asymmetric unit of the title compound, [ErCl(3)(C(10)H(17)Cl(3)N(3)O(2)P)(3)], contains two independent molecules. In each molecule, the Er(III) ion is six-coordinated in a slightly distorted octahedral ErO(3)Cl(3) geometry with a fac-arrangement of the donor atoms. Intramolecular N—H⋯Cl hyd...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984002/ https://www.ncbi.nlm.nih.gov/pubmed/21580536 http://dx.doi.org/10.1107/S1600536810010408 |
Sumario: | The asymmetric unit of the title compound, [ErCl(3)(C(10)H(17)Cl(3)N(3)O(2)P)(3)], contains two independent molecules. In each molecule, the Er(III) ion is six-coordinated in a slightly distorted octahedral ErO(3)Cl(3) geometry with a fac-arrangement of the donor atoms. Intramolecular N—H⋯Cl hydrogen bonds influence the molecular conformations. Some of the pyrrolidine fragments in the N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide ligands are disordered over two conformations of equal occupancy. The unusually porous crystal packing exhibits voids of 162, 158 and 13 Å(3 )and short intermolecular Cl⋯O contacts of 2.876 (3) and 3.022 (4) Å. |
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