Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]

In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from...

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Detalles Bibliográficos
Autores principales: Mohd Lair, Nooraziah, Khaledi, Hamid, Mohd Ali, Hapipah, Puteh, Rustam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984003/
https://www.ncbi.nlm.nih.gov/pubmed/21580553
http://dx.doi.org/10.1107/S1600536810011323
Descripción
Sumario:In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu—O inter­actions and also O—H⋯N hydrogen bonds.

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