Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]

In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from...

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Autores principales: Mohd Lair, Nooraziah, Khaledi, Hamid, Mohd Ali, Hapipah, Puteh, Rustam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984003/
https://www.ncbi.nlm.nih.gov/pubmed/21580553
http://dx.doi.org/10.1107/S1600536810011323
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author Mohd Lair, Nooraziah
Khaledi, Hamid
Mohd Ali, Hapipah
Puteh, Rustam
author_facet Mohd Lair, Nooraziah
Khaledi, Hamid
Mohd Ali, Hapipah
Puteh, Rustam
author_sort Mohd Lair, Nooraziah
collection PubMed
description In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu—O inter­actions and also O—H⋯N hydrogen bonds.
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spelling pubmed-29840032010-12-30 Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)] Mohd Lair, Nooraziah Khaledi, Hamid Mohd Ali, Hapipah Puteh, Rustam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu—O inter­actions and also O—H⋯N hydrogen bonds. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2984003/ /pubmed/21580553 http://dx.doi.org/10.1107/S1600536810011323 Text en © Mohd Lair et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mohd Lair, Nooraziah
Khaledi, Hamid
Mohd Ali, Hapipah
Puteh, Rustam
Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_full Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_fullStr Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_full_unstemmed Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_short Bis[μ-4-hydr­oxy-N′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_sort bis[μ-4-hydr­oxy-n′-(4-meth­oxy-2-oxido­benzyl­idene)benzohydrazidato]bis­[pyridine­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984003/
https://www.ncbi.nlm.nih.gov/pubmed/21580553
http://dx.doi.org/10.1107/S1600536810011323
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