9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O and C—F⋯π inter­act...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Sikorski, Artur, Malecha, Piotr, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984008/
https://www.ncbi.nlm.nih.gov/pubmed/21580656
http://dx.doi.org/10.1107/S1600536810008950
Descripción
Sumario:In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O and C—F⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 20.8 (1)°. The carboxyl group is twisted at an angle of 66.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel in the lattice.

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