9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O and C—F⋯π inter­act...

Descripción completa

Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Sikorski, Artur, Malecha, Piotr, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984008/
https://www.ncbi.nlm.nih.gov/pubmed/21580656
http://dx.doi.org/10.1107/S1600536810008950
_version_ 1782192011924733952
author Trzybiński, Damian
Krzymiński, Karol
Sikorski, Artur
Malecha, Piotr
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Krzymiński, Karol
Sikorski, Artur
Malecha, Piotr
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O and C—F⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 20.8 (1)°. The carboxyl group is twisted at an angle of 66.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel in the lattice.
format Text
id pubmed-2984008
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29840082010-12-30 9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Krzymiński, Karol Sikorski, Artur Malecha, Piotr Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O and C—F⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 20.8 (1)°. The carboxyl group is twisted at an angle of 66.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel in the lattice. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2984008/ /pubmed/21580656 http://dx.doi.org/10.1107/S1600536810008950 Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Krzymiński, Karol
Sikorski, Artur
Malecha, Piotr
Błażejowski, Jerzy
9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-(2-Ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-(2-ethyl­phenoxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984008/
https://www.ncbi.nlm.nih.gov/pubmed/21580656
http://dx.doi.org/10.1107/S1600536810008950
work_keys_str_mv AT trzybinskidamian 92ethylphenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT krzyminskikarol 92ethylphenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT sikorskiartur 92ethylphenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT malechapiotr 92ethylphenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 92ethylphenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate

Ejemplares similares