2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide

The asymmetric unit of the title compound, C(15)H(15)NO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the SO bonds. Further, the mol­ecules are twisted at the S atoms with torsion angles of −53.1 (2)...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Suchetan, P. A., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984015/
https://www.ncbi.nlm.nih.gov/pubmed/21580592
http://dx.doi.org/10.1107/S1600536810007440
Descripción
Sumario:The asymmetric unit of the title compound, C(15)H(15)NO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the SO bonds. Further, the mol­ecules are twisted at the S atoms with torsion angles of −53.1 (2) and 61.2 (2)° in the two mol­ecules. The dihedral angles between the sulfonyl benzene rings and the —SO(2)—NH—C—O segments are 86.0 (1) and 87.9 (1)°. Furthermore, the dihedral angles between the sulfonyl and the benzoyl benzene rings are 88.1 (1) and 83.5 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked by N—H⋯O(S) hydrogen bonds.

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