2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide

The asymmetric unit of the title compound, C(15)H(15)NO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the SO bonds. Further, the mol­ecules are twisted at the S atoms with torsion angles of −53.1 (2)...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Suchetan, P. A., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984015/
https://www.ncbi.nlm.nih.gov/pubmed/21580592
http://dx.doi.org/10.1107/S1600536810007440
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author Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The asymmetric unit of the title compound, C(15)H(15)NO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the SO bonds. Further, the mol­ecules are twisted at the S atoms with torsion angles of −53.1 (2) and 61.2 (2)° in the two mol­ecules. The dihedral angles between the sulfonyl benzene rings and the —SO(2)—NH—C—O segments are 86.0 (1) and 87.9 (1)°. Furthermore, the dihedral angles between the sulfonyl and the benzoyl benzene rings are 88.1 (1) and 83.5 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked by N—H⋯O(S) hydrogen bonds.
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spelling pubmed-29840152010-12-30 2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(15)NO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the SO bonds. Further, the mol­ecules are twisted at the S atoms with torsion angles of −53.1 (2) and 61.2 (2)° in the two mol­ecules. The dihedral angles between the sulfonyl benzene rings and the —SO(2)—NH—C—O segments are 86.0 (1) and 87.9 (1)°. Furthermore, the dihedral angles between the sulfonyl and the benzoyl benzene rings are 88.1 (1) and 83.5 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked by N—H⋯O(S) hydrogen bonds. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2984015/ /pubmed/21580592 http://dx.doi.org/10.1107/S1600536810007440 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide
title 2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide
title_full 2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide
title_fullStr 2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide
title_full_unstemmed 2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide
title_short 2-Methyl-N-(4-methyl­benzo­yl)benzene­sulfonamide
title_sort 2-methyl-n-(4-methyl­benzo­yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984015/
https://www.ncbi.nlm.nih.gov/pubmed/21580592
http://dx.doi.org/10.1107/S1600536810007440
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AT forosabine 2methyln4methylbenzoylbenzenesulfonamide
AT suchetanpa 2methyln4methylbenzoylbenzenesulfonamide
AT fuesshartmut 2methyln4methylbenzoylbenzenesulfonamide

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