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2-(1,3-Thia­zol-4-yl)benzimidazolium nitrate monohydrate

In the title compound, C(10)H(8)N(3)S(+)·NO(3) (−)·H(2)O, one of the N atoms of the benzimidazole unit is protonated, unlike than that in the thia­zole group. This protonation leads to equalization of the bond angles at the two N atoms of the benzimidazole group. The benzimidazole and thia­zole syst...

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Detalles Bibliográficos
Autores principales: Flores-Alamo, Marcos, González-Martínez, Sandra, Castillo-Blum, Silvia E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984023/
https://www.ncbi.nlm.nih.gov/pubmed/21580644
http://dx.doi.org/10.1107/S1600536810008433
Descripción
Sumario:In the title compound, C(10)H(8)N(3)S(+)·NO(3) (−)·H(2)O, one of the N atoms of the benzimidazole unit is protonated, unlike than that in the thia­zole group. This protonation leads to equalization of the bond angles at the two N atoms of the benzimidazole group. The benzimidazole and thia­zole systems are almost coplanar, forming a dihedral angle of 0.5 (2)°. In the crystal, the nitrate anion and water mol­ecule bridge the thia­bendazolium cations through N—H⋯O and O—H⋯O hydrogen bonds, leading to a supra­molecular network based on an infinite one-dimensional chain using [001] as base vector.