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2-(1,3-Thiazol-4-yl)benzimidazolium nitrate monohydrate
In the title compound, C(10)H(8)N(3)S(+)·NO(3) (−)·H(2)O, one of the N atoms of the benzimidazole unit is protonated, unlike than that in the thiazole group. This protonation leads to equalization of the bond angles at the two N atoms of the benzimidazole group. The benzimidazole and thiazole syst...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984023/ https://www.ncbi.nlm.nih.gov/pubmed/21580644 http://dx.doi.org/10.1107/S1600536810008433 |
Sumario: | In the title compound, C(10)H(8)N(3)S(+)·NO(3) (−)·H(2)O, one of the N atoms of the benzimidazole unit is protonated, unlike than that in the thiazole group. This protonation leads to equalization of the bond angles at the two N atoms of the benzimidazole group. The benzimidazole and thiazole systems are almost coplanar, forming a dihedral angle of 0.5 (2)°. In the crystal, the nitrate anion and water molecule bridge the thiabendazolium cations through N—H⋯O and O—H⋯O hydrogen bonds, leading to a supramolecular network based on an infinite one-dimensional chain using [001] as base vector. |
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