Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate

In the title mol­ecule, C(21)H(24)N(2)O(3), the imidazole ring is essentially planar, with a maxium deviation of 0.015 (1) Å. The dihedral angle between the benzene and imidazole rings is 65.47 (6)°. The crystal packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds, forming zi...

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Detalles Bibliográficos
Autores principales: Arumugam, Natarajan, Abd Hamid, Shafida, Abdul Rahim, Aisyah Saad, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984033/
https://www.ncbi.nlm.nih.gov/pubmed/21580619
http://dx.doi.org/10.1107/S1600536810007956
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author Arumugam, Natarajan
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Arumugam, Natarajan
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Arumugam, Natarajan
collection PubMed
description In the title mol­ecule, C(21)H(24)N(2)O(3), the imidazole ring is essentially planar, with a maxium deviation of 0.015 (1) Å. The dihedral angle between the benzene and imidazole rings is 65.47 (6)°. The crystal packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds, forming zigzag chains along the c axis. The crystal structure is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-29840332010-12-30 Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate Arumugam, Natarajan Abd Hamid, Shafida Abdul Rahim, Aisyah Saad Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(21)H(24)N(2)O(3), the imidazole ring is essentially planar, with a maxium deviation of 0.015 (1) Å. The dihedral angle between the benzene and imidazole rings is 65.47 (6)°. The crystal packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds, forming zigzag chains along the c axis. The crystal structure is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2984033/ /pubmed/21580619 http://dx.doi.org/10.1107/S1600536810007956 Text en © Arumugam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arumugam, Natarajan
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
Hemamalini, Madhukar
Fun, Hoong-Kun
Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_full Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_fullStr Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_full_unstemmed Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_short Ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_sort ethyl 1-tert-butyl-2-(4-methoxy­phen­yl)-1h-benzimidazole-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984033/
https://www.ncbi.nlm.nih.gov/pubmed/21580619
http://dx.doi.org/10.1107/S1600536810007956
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