Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate

In the title compound, Na(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one of the water mol­ecules lies on a twofold axis. There is no inter­action between the N atom and the sodium ion. The sodium ion exhibits a pseudo-octa­hedral coordination defined by three water O atoms and three sulfonyl O atoms from t...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984040/
https://www.ncbi.nlm.nih.gov/pubmed/21580706
http://dx.doi.org/10.1107/S1600536810009864
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author Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, Na(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one of the water mol­ecules lies on a twofold axis. There is no inter­action between the N atom and the sodium ion. The sodium ion exhibits a pseudo-octa­hedral coordination defined by three water O atoms and three sulfonyl O atoms from three different anions. The S—N distance of 1.588 (2) Å is consistent with an S=N double bond. The crystal structure is stabilized by O—H⋯N and O—H⋯Cl hydrogen bonds.
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spelling pubmed-29840402010-12-30 Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Shakuntala, K. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, Na(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one of the water mol­ecules lies on a twofold axis. There is no inter­action between the N atom and the sodium ion. The sodium ion exhibits a pseudo-octa­hedral coordination defined by three water O atoms and three sulfonyl O atoms from three different anions. The S—N distance of 1.588 (2) Å is consistent with an S=N double bond. The crystal structure is stabilized by O—H⋯N and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2984040/ /pubmed/21580706 http://dx.doi.org/10.1107/S1600536810009864 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Fuess, Hartmut
Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_full Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_fullStr Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_full_unstemmed Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_short Sodium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_sort sodium n,2-dichloro­benzene­sulfonamidate sesquihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984040/
https://www.ncbi.nlm.nih.gov/pubmed/21580706
http://dx.doi.org/10.1107/S1600536810009864
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AT fuesshartmut sodiumn2dichlorobenzenesulfonamidatesesquihydrate

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