Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)

The title complex, [Cu(2)(C(13)H(11)F(2)N(6)O)(2)](ClO(4))(2), which was hydro­thermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu(2)O(2) rhombus [Cu—O = 1.927 (2) Å] formed by donation of two O atoms from two chelate rings. The tridentate function of each ligand is com...

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Autores principales: Luo, Zhi-Rong, Hu, Fei-Long, Zhuang, Yue, Yin, Xian-Hong, Wu, Qiao-Lan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984043/
https://www.ncbi.nlm.nih.gov/pubmed/21580497
http://dx.doi.org/10.1107/S1600536810008512
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author Luo, Zhi-Rong
Hu, Fei-Long
Zhuang, Yue
Yin, Xian-Hong
Wu, Qiao-Lan
author_facet Luo, Zhi-Rong
Hu, Fei-Long
Zhuang, Yue
Yin, Xian-Hong
Wu, Qiao-Lan
author_sort Luo, Zhi-Rong
collection PubMed
description The title complex, [Cu(2)(C(13)H(11)F(2)N(6)O)(2)](ClO(4))(2), which was hydro­thermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu(2)O(2) rhombus [Cu—O = 1.927 (2) Å] formed by donation of two O atoms from two chelate rings. The tridentate function of each ligand is completed by two N atoms coordinated to the two Cu(II) atoms [Cu—N = 1.933 (2) Å]. The separation distance of two Cu(II) atoms in a cluster is 2.988 (1) Å. The dihedral angle between the six-membered chelate rings is 2.13 (9)°. The perchlorate counter-anion is disordered over two sites in a 0.58 (10):0.42 (10) ratio.
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spelling pubmed-29840432010-12-30 Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate) Luo, Zhi-Rong Hu, Fei-Long Zhuang, Yue Yin, Xian-Hong Wu, Qiao-Lan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(13)H(11)F(2)N(6)O)(2)](ClO(4))(2), which was hydro­thermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu(2)O(2) rhombus [Cu—O = 1.927 (2) Å] formed by donation of two O atoms from two chelate rings. The tridentate function of each ligand is completed by two N atoms coordinated to the two Cu(II) atoms [Cu—N = 1.933 (2) Å]. The separation distance of two Cu(II) atoms in a cluster is 2.988 (1) Å. The dihedral angle between the six-membered chelate rings is 2.13 (9)°. The perchlorate counter-anion is disordered over two sites in a 0.58 (10):0.42 (10) ratio. International Union of Crystallography 2010-03-10 /pmc/articles/PMC2984043/ /pubmed/21580497 http://dx.doi.org/10.1107/S1600536810008512 Text en © Luo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Zhi-Rong
Hu, Fei-Long
Zhuang, Yue
Yin, Xian-Hong
Wu, Qiao-Lan
Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)
title Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)
title_full Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)
title_fullStr Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)
title_full_unstemmed Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)
title_short Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis­(perchlorate)
title_sort bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1h-1,2,4-triazol-1-yl)propan-2-olato]dicopper(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984043/
https://www.ncbi.nlm.nih.gov/pubmed/21580497
http://dx.doi.org/10.1107/S1600536810008512
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