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Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate

The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetra­nuclear palladium core with four bridging chlorido ligands and two bridging methyl­ene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetra­nuclear complex can be considered as be...

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Autores principales: Schnetz, Thomas, Rominger, Frank, Hofmann, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984049/
https://www.ncbi.nlm.nih.gov/pubmed/21580540
http://dx.doi.org/10.1107/S1600536810010263
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author Schnetz, Thomas
Rominger, Frank
Hofmann, Peter
author_facet Schnetz, Thomas
Rominger, Frank
Hofmann, Peter
author_sort Schnetz, Thomas
collection PubMed
description The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetra­nuclear palladium core with four bridging chlorido ligands and two bridging methyl­ene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetra­nuclear complex can be considered as being composed of two μ-chlorido-bridged LPd(2) units. The structural motif of these LPd(2) units shows two doubly bridged palladium centers between the P atoms of the bis-phosphine ligand. One of these bridges is a μ-Cl atom, the other a μ-methyl­ene group. The coordination environment around each palladium center is essentially square planar. We ascribe the oxidation state +II to the palladium centers and do not assume Pd—Pd bonds [shortest distances 2.8110 (5) and 2.8109 (6) Å]. Co-crystallized with the palladium complex we found five non-coordinating tetra­hydro­furan solvent mol­ecules, one of which is disordered over two positions in a 0.429 (9):0.571 (8) ratio.
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spelling pubmed-29840492010-12-30 Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate Schnetz, Thomas Rominger, Frank Hofmann, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetra­nuclear palladium core with four bridging chlorido ligands and two bridging methyl­ene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetra­nuclear complex can be considered as being composed of two μ-chlorido-bridged LPd(2) units. The structural motif of these LPd(2) units shows two doubly bridged palladium centers between the P atoms of the bis-phosphine ligand. One of these bridges is a μ-Cl atom, the other a μ-methyl­ene group. The coordination environment around each palladium center is essentially square planar. We ascribe the oxidation state +II to the palladium centers and do not assume Pd—Pd bonds [shortest distances 2.8110 (5) and 2.8109 (6) Å]. Co-crystallized with the palladium complex we found five non-coordinating tetra­hydro­furan solvent mol­ecules, one of which is disordered over two positions in a 0.429 (9):0.571 (8) ratio. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984049/ /pubmed/21580540 http://dx.doi.org/10.1107/S1600536810010263 Text en © Schnetz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schnetz, Thomas
Rominger, Frank
Hofmann, Peter
Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate
title Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate
title_full Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate
title_fullStr Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate
title_full_unstemmed Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate
title_short Di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) P:P′]-μ-chlorido-μ-methyl­idene-dipalladium(II)} tetra­hydro­furan penta­solvate
title_sort di-μ-chlorido-bis­{[μ-1,8-bis­(diisopropyl­phosphan­yl)-9,10-dihydro-9,10-ethano­anthracene-κ(2) p:p′]-μ-chlorido-μ-methyl­idene-dipalladium(ii)} tetra­hydro­furan penta­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984049/
https://www.ncbi.nlm.nih.gov/pubmed/21580540
http://dx.doi.org/10.1107/S1600536810010263
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