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Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2) P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate
The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetranuclear palladium core with four bridging chlorido ligands and two bridging methylene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetranuclear complex can be considered as be...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984049/ https://www.ncbi.nlm.nih.gov/pubmed/21580540 http://dx.doi.org/10.1107/S1600536810010263 |
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author | Schnetz, Thomas Rominger, Frank Hofmann, Peter |
author_facet | Schnetz, Thomas Rominger, Frank Hofmann, Peter |
author_sort | Schnetz, Thomas |
collection | PubMed |
description | The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetranuclear palladium core with four bridging chlorido ligands and two bridging methylene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetranuclear complex can be considered as being composed of two μ-chlorido-bridged LPd(2) units. The structural motif of these LPd(2) units shows two doubly bridged palladium centers between the P atoms of the bis-phosphine ligand. One of these bridges is a μ-Cl atom, the other a μ-methylene group. The coordination environment around each palladium center is essentially square planar. We ascribe the oxidation state +II to the palladium centers and do not assume Pd—Pd bonds [shortest distances 2.8110 (5) and 2.8109 (6) Å]. Co-crystallized with the palladium complex we found five non-coordinating tetrahydrofuran solvent molecules, one of which is disordered over two positions in a 0.429 (9):0.571 (8) ratio. |
format | Text |
id | pubmed-2984049 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29840492010-12-30 Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2) P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate Schnetz, Thomas Rominger, Frank Hofmann, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetranuclear palladium core with four bridging chlorido ligands and two bridging methylene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetranuclear complex can be considered as being composed of two μ-chlorido-bridged LPd(2) units. The structural motif of these LPd(2) units shows two doubly bridged palladium centers between the P atoms of the bis-phosphine ligand. One of these bridges is a μ-Cl atom, the other a μ-methylene group. The coordination environment around each palladium center is essentially square planar. We ascribe the oxidation state +II to the palladium centers and do not assume Pd—Pd bonds [shortest distances 2.8110 (5) and 2.8109 (6) Å]. Co-crystallized with the palladium complex we found five non-coordinating tetrahydrofuran solvent molecules, one of which is disordered over two positions in a 0.429 (9):0.571 (8) ratio. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984049/ /pubmed/21580540 http://dx.doi.org/10.1107/S1600536810010263 Text en © Schnetz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Schnetz, Thomas Rominger, Frank Hofmann, Peter Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2) P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate |
title | Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2)
P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate |
title_full | Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2)
P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate |
title_fullStr | Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2)
P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate |
title_full_unstemmed | Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2)
P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate |
title_short | Di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2)
P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate |
title_sort | di-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ(2)
p:p′]-μ-chlorido-μ-methylidene-dipalladium(ii)} tetrahydrofuran pentasolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984049/ https://www.ncbi.nlm.nih.gov/pubmed/21580540 http://dx.doi.org/10.1107/S1600536810010263 |
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