Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate

Previously reported at a temperature of 298 (2) K [Lee & Joo (2007 ▶). Acta Cryst. E63, i11–i13], the title compound, K(7)[H(9)α-Pt(2)Mo(12)O(48)]·11H(2)O or K(7)[H(4.5)α-PtMo(6)O(24)](2)·11H(2)O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that cr...

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Detalles Bibliográficos
Autores principales: Lee, Uk, Joo, Hea-Chung, Park, Ki-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984051/
https://www.ncbi.nlm.nih.gov/pubmed/21580460
http://dx.doi.org/10.1107/S1600536810008639
Descripción
Sumario:Previously reported at a temperature of 298 (2) K [Lee & Joo (2007 ▶). Acta Cryst. E63, i11–i13], the title compound, K(7)[H(9)α-Pt(2)Mo(12)O(48)]·11H(2)O or K(7)[H(4.5)α-PtMo(6)O(24)](2)·11H(2)O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that crosses the center of symmetry was located at the center of symmetry or disordered around it as assumed in the previous study. During the present low-temperature study it was found on the center of symmetry. One water molecule shows half-occupancy.

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