Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate

Previously reported at a temperature of 298 (2) K [Lee & Joo (2007 ▶). Acta Cryst. E63, i11–i13], the title compound, K(7)[H(9)α-Pt(2)Mo(12)O(48)]·11H(2)O or K(7)[H(4.5)α-PtMo(6)O(24)](2)·11H(2)O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that cr...

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Detalles Bibliográficos
Autores principales: Lee, Uk, Joo, Hea-Chung, Park, Ki-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984051/
https://www.ncbi.nlm.nih.gov/pubmed/21580460
http://dx.doi.org/10.1107/S1600536810008639
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author Lee, Uk
Joo, Hea-Chung
Park, Ki-Min
author_facet Lee, Uk
Joo, Hea-Chung
Park, Ki-Min
author_sort Lee, Uk
collection PubMed
description Previously reported at a temperature of 298 (2) K [Lee & Joo (2007 ▶). Acta Cryst. E63, i11–i13], the title compound, K(7)[H(9)α-Pt(2)Mo(12)O(48)]·11H(2)O or K(7)[H(4.5)α-PtMo(6)O(24)](2)·11H(2)O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that crosses the center of symmetry was located at the center of symmetry or disordered around it as assumed in the previous study. During the present low-temperature study it was found on the center of symmetry. One water molecule shows half-occupancy.
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spelling pubmed-29840512010-12-30 Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate Lee, Uk Joo, Hea-Chung Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Previously reported at a temperature of 298 (2) K [Lee & Joo (2007 ▶). Acta Cryst. E63, i11–i13], the title compound, K(7)[H(9)α-Pt(2)Mo(12)O(48)]·11H(2)O or K(7)[H(4.5)α-PtMo(6)O(24)](2)·11H(2)O, was redetermined at 146 (2) K in order to determine whether the H atom in the hydrogen bond that crosses the center of symmetry was located at the center of symmetry or disordered around it as assumed in the previous study. During the present low-temperature study it was found on the center of symmetry. One water molecule shows half-occupancy. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2984051/ /pubmed/21580460 http://dx.doi.org/10.1107/S1600536810008639 Text en © Lee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Lee, Uk
Joo, Hea-Chung
Park, Ki-Min
Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate
title Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate
title_full Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate
title_fullStr Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate
title_full_unstemmed Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate
title_short Redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(IV)] undeca­hydrate
title_sort redetermination of hepta­potassium nona­hydrogen bis­[α-hexa­molybdoplatinate(iv)] undeca­hydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984051/
https://www.ncbi.nlm.nih.gov/pubmed/21580460
http://dx.doi.org/10.1107/S1600536810008639
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