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(2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate

In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the mol­ecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbony...

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Detalles Bibliográficos
Autores principales: Kaczmarek, Krzysztof, Wojciechowski, Jakub, Wolf, Wojciech M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984054/
https://www.ncbi.nlm.nih.gov/pubmed/21580659
http://dx.doi.org/10.1107/S1600536810004277
Descripción
Sumario:In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the mol­ecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbonyl O atom, with an r.m.s. deviation from the mean plane of 0.06 Å. The carboxyl­ate substituent is located axially, while the ammonium group occupies an equatorial position. In the crystal structure, the mol­ecules are linked through N—H⋯O hydrogen bonds, forming a three-dimensional network.