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(2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the molecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbony...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984054/ https://www.ncbi.nlm.nih.gov/pubmed/21580659 http://dx.doi.org/10.1107/S1600536810004277 |
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author | Kaczmarek, Krzysztof Wojciechowski, Jakub Wolf, Wojciech M. |
author_facet | Kaczmarek, Krzysztof Wojciechowski, Jakub Wolf, Wojciech M. |
author_sort | Kaczmarek, Krzysztof |
collection | PubMed |
description | In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the molecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbonyl O atom, with an r.m.s. deviation from the mean plane of 0.06 Å. The carboxylate substituent is located axially, while the ammonium group occupies an equatorial position. In the crystal structure, the molecules are linked through N—H⋯O hydrogen bonds, forming a three-dimensional network. |
format | Text |
id | pubmed-2984054 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29840542010-12-30 (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate Kaczmarek, Krzysztof Wojciechowski, Jakub Wolf, Wojciech M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the molecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbonyl O atom, with an r.m.s. deviation from the mean plane of 0.06 Å. The carboxylate substituent is located axially, while the ammonium group occupies an equatorial position. In the crystal structure, the molecules are linked through N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2984054/ /pubmed/21580659 http://dx.doi.org/10.1107/S1600536810004277 Text en © Kaczmarek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kaczmarek, Krzysztof Wojciechowski, Jakub Wolf, Wojciech M. (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate |
title | (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate |
title_full | (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate |
title_fullStr | (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate |
title_full_unstemmed | (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate |
title_short | (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate |
title_sort | (2s,4r)-4-ammonio-5-oxopyrrolidine-2-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984054/ https://www.ncbi.nlm.nih.gov/pubmed/21580659 http://dx.doi.org/10.1107/S1600536810004277 |
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