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(2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate

In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the mol­ecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbony...

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Detalles Bibliográficos
Autores principales: Kaczmarek, Krzysztof, Wojciechowski, Jakub, Wolf, Wojciech M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984054/
https://www.ncbi.nlm.nih.gov/pubmed/21580659
http://dx.doi.org/10.1107/S1600536810004277
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author Kaczmarek, Krzysztof
Wojciechowski, Jakub
Wolf, Wojciech M.
author_facet Kaczmarek, Krzysztof
Wojciechowski, Jakub
Wolf, Wojciech M.
author_sort Kaczmarek, Krzysztof
collection PubMed
description In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the mol­ecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbonyl O atom, with an r.m.s. deviation from the mean plane of 0.06 Å. The carboxyl­ate substituent is located axially, while the ammonium group occupies an equatorial position. In the crystal structure, the mol­ecules are linked through N—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29840542010-12-30 (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate Kaczmarek, Krzysztof Wojciechowski, Jakub Wolf, Wojciech M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(5)H(8)N(2)O(3), the mol­ecules exist in the zwitterionic form. The pyrrolidine ring adopts an envelope conformation with the unsubstituted endocyclic C atom situated at the flap. The other four endocyclic atoms are coplanar with the exocyclic carbonyl O atom, with an r.m.s. deviation from the mean plane of 0.06 Å. The carboxyl­ate substituent is located axially, while the ammonium group occupies an equatorial position. In the crystal structure, the mol­ecules are linked through N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2984054/ /pubmed/21580659 http://dx.doi.org/10.1107/S1600536810004277 Text en © Kaczmarek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kaczmarek, Krzysztof
Wojciechowski, Jakub
Wolf, Wojciech M.
(2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
title (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
title_full (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
title_fullStr (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
title_full_unstemmed (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
title_short (2S,4R)-4-Ammonio-5-oxopyrrolidine-2-carboxylate
title_sort (2s,4r)-4-ammonio-5-oxopyrrolidine-2-carboxylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984054/
https://www.ncbi.nlm.nih.gov/pubmed/21580659
http://dx.doi.org/10.1107/S1600536810004277
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