Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate

In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio­cyanate ligands in a distorted tetra­hedral configuration. The crystal...

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Detalles Bibliográficos
Autores principales: Khumalo, Nozipho M., Meijboom, Reinout, Muller, Alfred, Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984055/
https://www.ncbi.nlm.nih.gov/pubmed/21580539
http://dx.doi.org/10.1107/S1600536810010032
Descripción
Sumario:In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio­cyanate ligands in a distorted tetra­hedral configuration. The crystal structure exhibits inter­molecular C—H⋯π inter­actions.

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