Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate

In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio­cyanate ligands in a distorted tetra­hedral configuration. The crystal...

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Detalles Bibliográficos
Autores principales: Khumalo, Nozipho M., Meijboom, Reinout, Muller, Alfred, Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984055/
https://www.ncbi.nlm.nih.gov/pubmed/21580539
http://dx.doi.org/10.1107/S1600536810010032
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author Khumalo, Nozipho M.
Meijboom, Reinout
Muller, Alfred
Omondi, Bernard
author_facet Khumalo, Nozipho M.
Meijboom, Reinout
Muller, Alfred
Omondi, Bernard
author_sort Khumalo, Nozipho M.
collection PubMed
description In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio­cyanate ligands in a distorted tetra­hedral configuration. The crystal structure exhibits inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29840552010-12-30 Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate Khumalo, Nozipho M. Meijboom, Reinout Muller, Alfred Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio­cyanate ligands in a distorted tetra­hedral configuration. The crystal structure exhibits inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984055/ /pubmed/21580539 http://dx.doi.org/10.1107/S1600536810010032 Text en © Khumalo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khumalo, Nozipho M.
Meijboom, Reinout
Muller, Alfred
Omondi, Bernard
Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate
title Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate
title_full Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate
title_fullStr Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate
title_full_unstemmed Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate
title_short Di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(I)] 0.35-hydrate
title_sort di-μ-thio­cyanato-bis­[bis­(tri-p-tolyl­phosphine)silver(i)] 0.35-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984055/
https://www.ncbi.nlm.nih.gov/pubmed/21580539
http://dx.doi.org/10.1107/S1600536810010032
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AT mulleralfred dimthiocyanatobisbistriptolylphosphinesilveri035hydrate
AT omondibernard dimthiocyanatobisbistriptolylphosphinesilveri035hydrate

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