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Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)

The asymmetric unit of the title Co(II) complex, [Co(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains two half complex mol­ecules with similar structures. The Co(II) atoms are each located on an inversion center and each is coordinated by two 4-methyl­amino­benzoate (PMAB), two nicotinamide...

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Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Aybirdi, Özgür, Tercan, Barış, Ermiş, Emel, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984056/
https://www.ncbi.nlm.nih.gov/pubmed/21580537
http://dx.doi.org/10.1107/S1600536810010706
Descripción
Sumario:The asymmetric unit of the title Co(II) complex, [Co(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains two half complex mol­ecules with similar structures. The Co(II) atoms are each located on an inversion center and each is coordinated by two 4-methyl­amino­benzoate (PMAB), two nicotinamide (NA) ligands and two water mol­ecules in a distorted octa­hedral coordination. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure.