Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)

The asymmetric unit of the title Co(II) complex, [Co(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains two half complex mol­ecules with similar structures. The Co(II) atoms are each located on an inversion center and each is coordinated by two 4-methyl­amino­benzoate (PMAB), two nicotinamide...

Descripción completa

Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Aybirdi, Özgür, Tercan, Barış, Ermiş, Emel, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984056/
https://www.ncbi.nlm.nih.gov/pubmed/21580537
http://dx.doi.org/10.1107/S1600536810010706
_version_ 1782192023595384832
author Necefoğlu, Hacali
Aybirdi, Özgür
Tercan, Barış
Ermiş, Emel
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Aybirdi, Özgür
Tercan, Barış
Ermiş, Emel
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description The asymmetric unit of the title Co(II) complex, [Co(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains two half complex mol­ecules with similar structures. The Co(II) atoms are each located on an inversion center and each is coordinated by two 4-methyl­amino­benzoate (PMAB), two nicotinamide (NA) ligands and two water mol­ecules in a distorted octa­hedral coordination. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure.
format Text
id pubmed-2984056
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29840562010-12-30 Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II) Necefoğlu, Hacali Aybirdi, Özgür Tercan, Barış Ermiş, Emel Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title Co(II) complex, [Co(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains two half complex mol­ecules with similar structures. The Co(II) atoms are each located on an inversion center and each is coordinated by two 4-methyl­amino­benzoate (PMAB), two nicotinamide (NA) ligands and two water mol­ecules in a distorted octa­hedral coordination. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984056/ /pubmed/21580537 http://dx.doi.org/10.1107/S1600536810010706 Text en © Necefoğlu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Aybirdi, Özgür
Tercan, Barış
Ermiş, Emel
Hökelek, Tuncer
Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_fullStr Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full_unstemmed Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_short Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_sort diaqua­bis(4-methyl­amino­benzoato-κo)bis­(nicotinamide-κn (1))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984056/
https://www.ncbi.nlm.nih.gov/pubmed/21580537
http://dx.doi.org/10.1107/S1600536810010706
work_keys_str_mv AT necefogluhacali diaquabis4methylaminobenzoatokobisnicotinamidekn1cobaltii
AT aybirdiozgur diaquabis4methylaminobenzoatokobisnicotinamidekn1cobaltii
AT tercanbarıs diaquabis4methylaminobenzoatokobisnicotinamidekn1cobaltii
AT ermisemel diaquabis4methylaminobenzoatokobisnicotinamidekn1cobaltii
AT hokelektuncer diaquabis4methylaminobenzoatokobisnicotinamidekn1cobaltii

Ejemplares similares