Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate

In the title compound, K(+)·C(6)H(8)NO(4) (−), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl­ene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The ort...

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Detalles Bibliográficos
Autores principales: Reuter, Cédric, Neudörfl, Jörg M., Schmalz, Hans-Günther
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984059/
https://www.ncbi.nlm.nih.gov/pubmed/21580546
http://dx.doi.org/10.1107/S1600536810010159
Descripción
Sumario:In the title compound, K(+)·C(6)H(8)NO(4) (−), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl­ene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound.

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