Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate

In the title compound, K(+)·C(6)H(8)NO(4) (−), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl­ene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The ort...

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Detalles Bibliográficos
Autores principales: Reuter, Cédric, Neudörfl, Jörg M., Schmalz, Hans-Günther
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984059/
https://www.ncbi.nlm.nih.gov/pubmed/21580546
http://dx.doi.org/10.1107/S1600536810010159
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author Reuter, Cédric
Neudörfl, Jörg M.
Schmalz, Hans-Günther
author_facet Reuter, Cédric
Neudörfl, Jörg M.
Schmalz, Hans-Günther
author_sort Reuter, Cédric
collection PubMed
description In the title compound, K(+)·C(6)H(8)NO(4) (−), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl­ene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound.
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spelling pubmed-29840592010-12-30 Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate Reuter, Cédric Neudörfl, Jörg M. Schmalz, Hans-Günther Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K(+)·C(6)H(8)NO(4) (−), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl­ene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984059/ /pubmed/21580546 http://dx.doi.org/10.1107/S1600536810010159 Text en © Reuter et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reuter, Cédric
Neudörfl, Jörg M.
Schmalz, Hans-Günther
Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
title Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
title_full Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
title_fullStr Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
title_full_unstemmed Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
title_short Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
title_sort potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984059/
https://www.ncbi.nlm.nih.gov/pubmed/21580546
http://dx.doi.org/10.1107/S1600536810010159
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AT schmalzhansgunther potassium1methoxycarbonyl2methylprop2en2ylideneazinate

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