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Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)

The title Ni(II) complex, [Ni(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom located on an inversion center. The mol­ecule contains two 4-methyl­benzoate (PMB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. T...

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Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Çimen, Efdal, Tercan, Barış, Ermiş, Emel, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984063/
https://www.ncbi.nlm.nih.gov/pubmed/21580476
http://dx.doi.org/10.1107/S1600536810007385
Descripción
Sumario:The title Ni(II) complex, [Ni(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom located on an inversion center. The mol­ecule contains two 4-methyl­benzoate (PMB) and two nicotinamide (NA) ligands and two coordinated water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 26.15 (10)°, while the pyridine and benzene rings are oriented at a dihedral angle of 87.81 (4)°. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.896 (1) Å] may further stabilize the crystal structure. A weak C—H⋯π inter­action involving the pyridine ring also occurs.