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Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN (1))nickel(II)
The title Ni(II) complex, [Ni(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom located on an inversion center. The molecule contains two 4-methylbenzoate (PMB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. T...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984063/ https://www.ncbi.nlm.nih.gov/pubmed/21580476 http://dx.doi.org/10.1107/S1600536810007385 |
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author | Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Ermiş, Emel Hökelek, Tuncer |
author_facet | Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Ermiş, Emel Hökelek, Tuncer |
author_sort | Necefoğlu, Hacali |
collection | PubMed |
description | The title Ni(II) complex, [Ni(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom located on an inversion center. The molecule contains two 4-methylbenzoate (PMB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 26.15 (10)°, while the pyridine and benzene rings are oriented at a dihedral angle of 87.81 (4)°. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.896 (1) Å] may further stabilize the crystal structure. A weak C—H⋯π interaction involving the pyridine ring also occurs. |
format | Text |
id | pubmed-2984063 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29840632010-12-30 Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN (1))nickel(II) Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Ermiş, Emel Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Ni(II) complex, [Ni(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric with the Ni atom located on an inversion center. The molecule contains two 4-methylbenzoate (PMB) and two nicotinamide (NA) ligands and two coordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 26.15 (10)°, while the pyridine and benzene rings are oriented at a dihedral angle of 87.81 (4)°. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network. The π–π contact between the benzene rings [centroid–centroid distance = 3.896 (1) Å] may further stabilize the crystal structure. A weak C—H⋯π interaction involving the pyridine ring also occurs. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2984063/ /pubmed/21580476 http://dx.doi.org/10.1107/S1600536810007385 Text en © Necefoğlu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Ermiş, Emel Hökelek, Tuncer Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN (1))nickel(II) |
title | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_full | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_fullStr | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_full_unstemmed | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_short | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_sort | diaquabis(4-methylbenzoato-κo)bis(nicotinamide-κn
(1))nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984063/ https://www.ncbi.nlm.nih.gov/pubmed/21580476 http://dx.doi.org/10.1107/S1600536810007385 |
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